OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI8th EditionButler Publisher: IACCENGAGEISBN: 9781305271579
OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI
Solutions for OWLV2 FOR OXTOBY/GILLIS/BUTLER'S PRINCI
Problem 1P:
Determine the number of nodes along the internuclearaxis for each of the molecular orbitals for H2+...Problem 2P:
Determine the number of nodes along the internuclearaxis and the number of nodal planes for each of...Problem 3P:
Sketch the shape of each of the molecular orbitals for H2+ shown in Figure 6.5 in a plane...Problem 4P:
Sketch the shape of each of the molecular orbitals for H2+ shown in Figure 6.5 in a plane...Problem 5P:
Compare the electron density in the 1g and 1u* molecular orbitals for H2+ shown in Figure 6.5 with...Problem 6P:
Explain why 1g is the ground state for H2+ . By combining your answer with the answer to Problem 5,...Problem 8P:
Predict the ground electronic state of the He22+ ion. What is the bond order? Will it be stable in...Problem 11P:
Without consulting tables of data, predict which species has the greater bond length, H2 or He2+ .Problem 12P:
Without consulting tables of data, predict which species has the greater bond length, He2+ or H2 .Problem 13P:
Without consulting tables of data, on the same graph sketch the effective potential energy curves...Problem 14P:
Without consulting tables of data, on the same graph sketch the effective potential energy curves...Problem 15P:
Suppose we supply enough energy to H2 to remove one of its electrons. Is the bond energy of the...Problem 16P:
Suppose we supply enough energy to He2+ to remove its most weakly bound electron. Is the bond energy...Problem 18P:
When one electron is added to an oxygen molecule, a superoxide ion (O2) is formed. The addition of...Problem 19P:
Predict the valence electron configuration and the total bond order for the molecule S2 , which...Problem 20P:
Predict the valence electron configuration and the total bond order for the molecule I2 . Will I2 be...Problem 22P:
For each of the following valence electron configurations of a homonuclear diatomic molecule or...Problem 23P:
For each of the electron configurations in Problem 21, determine whether the molecule or molecular...Problem 24P:
For each of the electron configurations in Problem 22, determine whether the molecule or molecular...Problem 25P:
Following the pattern of Figure 6.21, work out the correlation diagram for the CN molecule, showing...Problem 26P:
Following the pattern of Figure 6.21, work out the correlation diagram for the BeN molecule, showing...Problem 27P:
The bond length of the transient diatomic molecule CF is 1.291 Å; that of the molecular ion CF+ is...Problem 28P:
The compound nitrogen oxide (NO) forms when the nitrogen and oxygen in air are heated. Predict...Problem 29P:
What would be the electron configuration for a HeH molecular ion? What bond order would you predict?...Problem 30P:
The molecular ion HeH+ has an equilibrium bond length of 0.774 Å. Draw an electron correlation...Problem 33P:
The bond dissociation energies for the species NO, CF , and CF+ are ordered as CF+NOCF . Use MO...Problem 34P:
The ionization energy of CO is greater than that of NO. Explain this difference based on the...Problem 35P:
Photoelectron spectra were acquired from a sample of gaseous N2 using He(I) light with energy 21.22...Problem 36P:
Photoelectron spectra were acquired from a sample of gaseous O2 using X-ray radiation with...Problem 38P:
From the n=0 peaks in the photoelectron spectrum for O2 shown in the figure in Connections box,...Problem 39P:
The photoelectron spectrum of HBr has two main groups of peaks. The first has ionization energy...Problem 40P:
The photoelectron spectrum of CO has four major peaks with ionization energies of 14.5, 17.2, 20.1,...Problem 41P:
Write simple valence bond wave functions for the diatomic molecules Li2 and C2 . State the bond...Problem 42P:
Write simple valence bond wave functions for the diatomic molecules B2 and O2 . State the bond order...Problem 43P:
Both the simple VB model and the LCAO method predict that the bond order of Be2 is 0. Explain how...Problem 44P:
Both the simple VB model and the LCAO method predict that the bond order of Ne2 is 0. Explain how...Problem 45P:
Write simple valence bond wave functions for formation of bonds between B atoms and H atoms. What BH...Problem 46P:
Write simple valence bond wave functions for formation of bonds between C and H atoms. What CH...Problem 47P:
Write simple valence bond wave functions for the bonds in NH3 . What geometry does the VB model...Problem 48P:
Write simple valence bond wave functions for the bonds in H2O . What geometry does the VB model...Problem 49P:
Formulate a localized bond picture for the amide ion (NH2) . What hybridization do you expect the...Problem 50P:
Formulate a localized bond picture for the hydronium ion (H3O+) . What hybridization do you expect...Problem 52P:
Draw a Lewis electron dot diagram for each of the following molecules and ions. Formulate the...Problem 53P:
Describe the hybrid orbitals on the chlorine atom in the ClO3+ and ClO2+ molecular ions. Sketch the...Problem 54P:
Describe the hybrid orbitals on the chlorine atom in the ClO4 and ClO3 molecular ions. Sketch the...Problem 55P:
The sodium salt of the unfamiliar orthonitrate ion (NO43) has been prepared. What hybridization is...Problem 56P:
Describe the hybrid orbitals used by the carbon atom in NCCl . Predict the geometry of the molecule.Problem 57P:
Describe the bonding in the bent molecule NF2 . Predict its energy level diagram and electron...Problem 58P:
Describe the bonding in the bent molecule OF2 . Predict its energy level diagram and electron...Problem 59P:
The azide ion (N3) is a weakly bound molecular ion. Formulate its MO structure for localized s bonds...Problem 60P:
Formulate the MO structure of (NO2+) for localized bonds and de-localized bonds. Is it linear or...Problem 61P:
Discuss the nature of the bonding in the nitrite ion (NO2) . Draw the possible Lewis resonance...Problem 62P:
Discuss the nature of the bonding in the nitrate ion (NO3) . Draw the possible Lewis resonance...Problem 63P:
The pyridine molecule (C5H5N) is obtained by replacing one CH group in benzene with a nitrogen atom....Problem 64P:
For each of the following molecules, construct the MOs from the 2pz atomic orbitals perpendicular...Problem 65AP:
(a) Sketch the occupied MOs of the valence shell for the N2 molecule. Label the orbitals as or ...Problem 66AP:
Calcium carbide (CaC2) is an intermediate in the manufacturing of acetylene (C2H2) . It is the...Problem 67AP:
The B2 molecule is paramagnetic; show how this indicates that the energy ordering of the orbitals in...Problem 68AP:
The Be2 molecule has been detected experimentally. It has a bond length of 2.45 Å and a bond...Problem 70AP:
The molecular ion HeH+ has an equilibrium bond length of 0.774 Å. Draw an electron correlation...Problem 71AP:
The MO of the ground state of a heteronuclear diatomicmoleculeAB is mol=CAA+CBB If a bonding...Problem 72AP:
The stable molecular ion H3+ is triangular, with HH distances of 0.87 Å. Sketch the molecule and...Browse All Chapters of This Textbook
Chapter 1 - The Atom In Modern ChemistryChapter 2 - Chemical Formulas, Equations, And Reaction YieldsChapter 3 - Atomic Shells And Classical Models Of Chemical BondingChapter 4 - Introduction To Quantum MechanicsChapter 5 - Quantum Mechanics And Atomic StructureChapter 6 - Quantum Mechanics And Molecular StructureChapter 7 - Bonding In Organic MoleculesChapter 8 - Bonding In Transition Metal Compounds And Coordination ComplexesChapter 9 - The Gaseous StateChapter 10 - Solids, Liquids, And Phase Transitions
Chapter 11 - SolutionsChapter 12 - Thermodynamic Processes And ThermochemistryChapter 13 - Spontaneous Processes And Thermodynamic EquilibriumChapter 14 - Chemical EquilibriumChapter 15 - Acid–base EquilibriaChapter 16 - Solubility And Precipitation EquilibriaChapter 17 - ElectrochemistryChapter 18 - Chemical KineticsChapter 19 - Nuclear ChemistryChapter 20 - Molecular Spectroscopy And PhotochemistryChapter 21 - Structure And Bonding In SolidsChapter 22 - Inorganic MaterialsChapter 23 - Polymeric Materials And Soft Condensed MatterChapter A - Scientific Notation And Experimental Error
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