Sketch the shape of each of the σ molecular orbitals for H2+ shown in Figure 6.5 in a plane perpendicular to the internuclear axis located at the midpoint between the two nuclei. Repeat the sketches for a plane perpendicular to the internuclear axis located at a point one quarter of the distance between the two nuclei.
Formal Charges
Formal charges have an important role in organic chemistry since this concept helps us to know whether an atom in a molecule is neutral/bears a positive or negative charge. Even if some molecules are neutral, the atoms within that molecule need not be neutral atoms.
Polarity Of Water
In simple chemical terms, polarity refers to the separation of charges in a chemical species leading into formation of two polar ends which are positively charged end and negatively charged end. Polarity in any molecule occurs due to the differences in the electronegativities of the bonded atoms. Water, as we all know has two hydrogen atoms bonded to an oxygen atom. As oxygen is more electronegative than hydrogen thus, there exists polarity in the bonds which is why water is known as a polar solvent.
Valence Bond Theory Vbt
Valence bond theory (VBT) in simple terms explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. It gives a quantum mechanical approach to the formation of covalent bonds with the help of wavefunctions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.
Sketch the shape of each of the σ molecular orbitals for H2+ shown in Figure 6.5 in a plane perpendicular to the internuclear axis located at the midpoint between the two nuclei. Repeat the sketches for a plane perpendicular to the internuclear axis located at a point one quarter of the distance between the two nuclei.
![FIGURE 6.5 Wave functions for the
first eight energy levels of the H;
molecular ion, calculated exactly by
quantum mechanics. The two nuclei
lie along the z-axis, which is in the
plane of the paper. Regions of
positive and negative amplitude are
shown in red and blue, respectively.
20
3o
The labels for each orbital are
explained in the text. The images are
isosurfaces corresponding to contours
at + 0.1 of the maximum amplitude.
The log is the ground state, and the
energies increase in the order lợg<
1ot< 20g < 2ơở< 1ĩy< 3og< 1nž<
3o. (Courtesy of Mr. Hatem Helal and
Professor William A. Goddand II, Califomia Institute of
Technology, and Dr. Kelly P. Gaither, University of Texas at
Austin.)
20g
1ng
30g
10g](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F52d0a961-30e3-43c4-8314-64c02bc8343a%2F4562d0e3-fe55-473a-8a63-f5796338bf8c%2Ft61yijh_processed.png&w=3840&q=75)
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