Organic Chemistry
Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter SRP, Problem 22P
Interpretation Introduction

Interpretation:

A stereoselective synthesis of methyl trans-4 isopropyl cyclohexanecarboxylate is to be outlined from phenol.

Concept Introduction:

Stereo selectivity is the property of chemical reactions where a reactant gives an unequal mixture of stereo isomeric products.

This arises due to difference in steric and electronic effects that leads to different products.

The efficiency of stereo selectivity lies totally with the stereochemistry of the products that are formed.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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