(a) Interpretation: The IUPAC name of the given ester is to be provided. Concept introduction: IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the − oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

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Answer 1

Question

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

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Answer 3

Question

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

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Answer 4

Question

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

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Answer 5

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 6

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 7

Chapter F, Problem F.22P

Interpretation Introduction

(a)

Interpretation:

The IUPAC name of the given ester is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given ester, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given compound, the IUPAC name is to be provided.

Concept introduction:

IUPAC names of esters are made up of two parts, alkyl/aryl alkanoate, with the −oate suffix indicating that it is an ester. The alkanoate part is derived from the carboxylic acid from which the ester is formed. The longest carbon chain including the carbonyl carbon determines the root name of molecule. The alkyl/aryl part of the name of the alkyl or aryl group attached to the non-carbonyl oxygen of the ester group. Any lower priority functional groups are treated as substituents and named in the prefix of the corresponding part.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The author explains that the IUPAC name of the given ester is propyl pentanoate.

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