(a) Interpretation: For the given nitrile, the IUPAC name is to be written. Concept introduction: The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

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Answer 1

Question

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

Predicting As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C - C bond as its major product: H₂N O H 1. ? 2. H3O+ If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. 0 If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. فا Explanation Check Click and drag to start drawing a structure.

Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers. OH OH OH OH OH OH

Answer 2

Question

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

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Answer 3

Question

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

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Answer 4

Question

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

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Answer 5

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

Answer 6

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Answer 7

Chapter F, Problem F.20P

Interpretation Introduction

(a)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If the root is a ring, the suffix carbonitrile is used. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number.

Answer 10

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

Answer 11

Interpretation Introduction

(c)

Interpretation:

For the given nitrile, the IUPAC name is to be written.

Concept introduction:

The IUPAC name of the given nitrile is made up of two parts. The first part is the root according to the longest carbon chain that includes the nitrile carbon or the ring to which the nitrile functional group is attached. This may include the name of any substituents present as a prefix. The suffix nitrile is simply appended to the root name instead of replacing the final e. If any chiral carbons are present, their absolute configuration is determined on the basis of Cahn-Ingold-Prelog rules and listed at the start along with the carbon number when necessary.

Answer 12

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Answer 15

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The author explains that the IUPAC name of the given nitrile is made up of two parts: the root and the suffix.

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