(a) Interpretation: The structure of 5-phenylpentanamide is to be drawn. Concept introduction: The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’. If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 1

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? NH2 MgBr Will the first product that forms in this reaction create a new CC bond? ○ Yes ○ No MgBr ? Will the first product that forms in this reaction create a new CC bond? O Yes O No Click and drag to start drawing a structure. :☐ G x c olo Ar HE

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Answer 2

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 3

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 4

Question

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

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Answer 5

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 6

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 7

Chapter F, Problem F.19P

Interpretation Introduction

(a)

Interpretation:

The structure of 5-phenylpentanamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of (2S, 3S)-2, 3-dimethoxyhexanediamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of N-phenylcyclobutanecarboxamide is to be drawn.

Concept introduction:

The structure of an amide can be drawn on the basis of its IUPAC name. The name consists of a root name indicating the longest continuous carbon chain that includes the carbonyl carbon of the amide group. Any prefixes present indicate the substituents on the alkyl chain or on the nitrogen if the locant is ‘N’.

If the amide contains a chiral center, the absolute configuration, R or S, is shown at the start, along with its locant.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. F - Prob. F.1P Ch. F - Prob. F.2P Ch. F - Prob. F.3P Ch. F - Prob. F.4P Ch. F - Prob. F.5P Ch. F - Prob. F.6P Ch. F - Prob. F.7P Ch. F - Prob. F.8P Ch. F - Prob. F.9P Ch. F - Prob. F.10P

Solution Summary: The structure of 5-phenylpentanamide is to be drawn on the basis of its IUPAC name.

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Chapter F Solutions