(a) Interpretation: The complete IUPAC name for the given molecule is to be written. Concept introduction: When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Question

4. C6H100 5 I peak 3 2 PPM Integration values: 1.79ppm (2), 4.43ppm (1.33) Ipeak

Answer 1

Question

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

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4. C6H100 5 I peak 3 2 PPM Integration values: 1.79ppm (2), 4.43ppm (1.33) Ipeak

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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly drawn and you should be able to tell that the bonding electrons and lone pair electrons should reside in which hybridized atomic orbital 2. You should consider ring strain- flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti- aromaticity) H H N N: NH2 N Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic TT electrons Me H Me Aromaticity (Circle) Aromatic Aromatic Aromatic Aromatic Aromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic aromatic πT electrons H HH…

Answer 2

Question

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

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Answer 3

Question

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

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Answer 4

Question

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

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Answer 5

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 6

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 7

Chapter C, Problem C.33P

Interpretation Introduction

(a)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment are compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The complete IUPAC name for the given molecule is to be written.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has a higher priority. In the case of comparison between isotopes, the one having the greater atomic mass gets the higher priority. If the substituents are attached by the same atom, then the set of atoms one bond away from the point of attachment is compared. In each set, the highest priority atoms are compared. If the sets of atoms one bond away from the point of attachment are identical, then the sets of atoms one additional bond away from the point of attachment are compared. If the higher priority groups attached to the double bonded carbon atoms are on the same side of the double bond, the alkene is assigned Z configuration. If the higher priority groups attached to the double bonded carbon atoms are on the opposite side of the double bond, the alkene is assigned E configuration. When more than one double bond is present, each is assigned E or Z configuration, and the location of each double bond appears immediately before the E or Z designation.

Answer 14

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Answer 25

Ch. C - Prob. C.1P Ch. C - Prob. C.2P Ch. C - Prob. C.3P Ch. C - Prob. C.4P Ch. C - Prob. C.5P Ch. C - Prob. C.6P Ch. C - Prob. C.7P Ch. C - Prob. C.8P Ch. C - Prob. C.9P Ch. C - Prob. C.10P

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Chapter C Solutions