(a) Interpretation: The molecular structure is to be drawn for the given name. Concept introduction: E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond. In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond. The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

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Answer 1

Question

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

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Answer 3

Question

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

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Answer 4

Question

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

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Answer 5

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 6

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 7

Chapter C, Problem C.36P

Interpretation Introduction

(a)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

In cyclic compounds with less than eight atoms, a ring double bond can have only one configuration, with the ring continuing on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The molecular structure is to be drawn for the given name.

Concept introduction:

E/Z designations indicate the absolute stereochemistry of double bonds. An E designation indicates the higher priority groups on the double bond are on opposite sides of the bond. A Z designation indicates that they are on the same side of the double bond.

The groups at each end of the double bond are assigned priorities on the basis of Cahn-Ingold-Prelog rules.

Answer 14

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Answer 25

Ch. C - Prob. C.1P Ch. C - Prob. C.2P Ch. C - Prob. C.3P Ch. C - Prob. C.4P Ch. C - Prob. C.5P Ch. C - Prob. C.6P Ch. C - Prob. C.7P Ch. C - Prob. C.8P Ch. C - Prob. C.9P Ch. C - Prob. C.10P

Solution Summary: The author explains the structure of (Z)-3-phenylhex-2-ene.

Chapter C Solutions