Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn. Concept Introduction: E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide . The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon . An E2 reaction is favoured by a high concentration of a strong base. An E1 reaction is favoured by a low concentration of a weak base.

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Answer 1

Question

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

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Draw the major and minor products for the following reaction. Identify the mechanism for each product (SN2, SN1, E2, E1). CI NaOMe

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Answer 2

Question

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

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Answer 3

Question

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

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Answer 4

Question

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

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Answer 5

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 6

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 7

Chapter 9.9, Problem 30P

(a)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Whether each of the given reaction are an E2 or an E1 occurs has to be decided and the major elimination product has to be drawn.

Concept Introduction:

E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

The alkyl halide dissociates to form a carbocation. The base abstract a proton from the β-carbon.

An E2 reaction is favoured by a high concentration of a strong base.

An E1 reaction is favoured by a low concentration of a weak base.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9.1 - Prob. 3P Ch. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.1 - Prob. 8P Ch. 9.2 - Prob. 9P Ch. 9.2 - Prob. 10P Ch. 9.2 - Prob. 11P Ch. 9.2 - Prob. 12P Ch. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 15P

Solution Summary: The author explains that E1 reaction is a unimolecular elimination reaction in which rate of the reaction depends on the concentration of alkyl halide.

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