Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 9.8, Problem 9.21CT
Your Turn 9.23 Scientific Practices Landfill Liners
Landfill liners include natural clay and human-made plastics. For example, thick sheets of high-density polyethylene may be employed. Even the best HDPE liners, however, can crack and degrade.
- a. From Table 9.1. which types of chemicals soften HDPE?
- b. Name five substances sent to the landfill that could degrade a HDPE liner over time.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 9 Solutions
Laboratory Manual Chemistry in Context
Ch. 9.1 - Scientific Practices Tennis Anyone? Examine this...Ch. 9.1 - Prob. 9.2CTCh. 9.4 - Prob. 9.4YTCh. 9.4 - Prob. 9.5CTCh. 9.4 - Prob. 9.6CTCh. 9.4 - Prob. 9.7CTCh. 9.4 - Prob. 9.8CTCh. 9.5 - Prob. 9.9CTCh. 9.5 - Prob. 9.11CTCh. 9.5 - Skill Building Polystyrene Possibilities Show the...
Ch. 9.6 - Skill Building Esters and Polyesters You have seen...Ch. 9.6 - Prob. 9.14CTCh. 9.7 - Skill Building Kevlar Kevlar is a polyamide used...Ch. 9.8 - Prob. 9.18CTCh. 9.8 - Your Turn 9.23 Scientific Practices Landfill...Ch. 9.9 - Prob. 9.23YTCh. 9.9 - Prob. 9.24CTCh. 9.11 - Your Turn 9.31 Scientific Practices Glass or...Ch. 9.11 - Prob. 9.29CTCh. 9.11 - Skill Building Meet DEHP DEHP belongs to a common...Ch. 9 - Prob. 1QCh. 9 - Prob. 2QCh. 9 - Prob. 3QCh. 9 - Prob. 4QCh. 9 - Prob. 5QCh. 9 - Prob. 6QCh. 9 - Prob. 7QCh. 9 - Prob. 8QCh. 9 - Prob. 9QCh. 9 - Prob. 10QCh. 9 - Prob. 11QCh. 9 - Prob. 12QCh. 9 - Prob. 13QCh. 9 - Prob. 14QCh. 9 - Prob. 15QCh. 9 - Prob. 16QCh. 9 - Prob. 17QCh. 9 - Prob. 18QCh. 9 - Prob. 19QCh. 9 - Prob. 20QCh. 9 - Prob. 21QCh. 9 - Prob. 22QCh. 9 - Prob. 23QCh. 9 - Prob. 24QCh. 9 - Prob. 25QCh. 9 - Prob. 26QCh. 9 - Prob. 27QCh. 9 - Prob. 28QCh. 9 - Prob. 29QCh. 9 - Prob. 30QCh. 9 - Prob. 31QCh. 9 - Prob. 32QCh. 9 - Prob. 33QCh. 9 - Prob. 34QCh. 9 - Prob. 35QCh. 9 - Prob. 36QCh. 9 - Prob. 37QCh. 9 - Prob. 38QCh. 9 - Prob. 39QCh. 9 - Prob. 40QCh. 9 - Prob. 41QCh. 9 - Prob. 42QCh. 9 - Prob. 43QCh. 9 - Prob. 44QCh. 9 - Prob. 45QCh. 9 - Prob. 46QCh. 9 - Prob. 47QCh. 9 - Prob. 48QCh. 9 - Prob. 49QCh. 9 - Prob. 50QCh. 9 - Prob. 51QCh. 9 - Prob. 52QCh. 9 - Prob. 53QCh. 9 - Prob. 54QCh. 9 - Prob. 55QCh. 9 - Prob. 56QCh. 9 - Prob. 57QCh. 9 - Prob. 58QCh. 9 - Prob. 59Q
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