Laboratory Manual Chemistry in Context
Laboratory Manual Chemistry in Context
8th Edition
ISBN: 9780073518121
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 9.5, Problem 9.12YT

Skill Building Polystyrene Possibilities

Show the arrangement of atoms in a polystyrene chain in the repeating head-to-tail arrangement. Why do you think this arrangement is favored rather than the head-to-head arrangement?

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5. Please draw in the blanks the missing transition states and the correlated products. Explicitly display relevant absolute stereochemical configuration. MeOH I OMe H Endo transition state, dienophile approaching from the bottom of diene + H ཎྞཾ ཌཱརཱ༔,_o OMe H H OMe Endo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) + Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) Exo transition state, dienophile approaching from the top of diene or from the bottom but horizontally flipped (draw one) MeO H H MeO H MeO H MeO H H
H H (1) H C. C C .H (2) (3) Cl H The ideal value for bond angle (1) is (Choose one) and the ideal value for bond angle (3) is (Choose one) degrees, the value for bond angle (2) is (Choose one) degrees, degrees.

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Laboratory Manual Chemistry in Context

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