Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Chapter 9.3, Problem 9.18P
Interpretation Introduction
Interpretation:
Efficient synthesis for the given transformation has to be suggested.
Concept Introduction:
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Propose syntheses for the product shown on the left starting from the indicated compound (shown on the right). Your answer should include a retrosynthetic analysis and a proposed synthetic route with reagents.
Benzyl acetate is a pleasant-smelling ester found in the essential oil of jasmine flowers and is used in many perfume formulations.
Starting with benzene and using any other reagents of your choice, design an efficient synthesis for benzyl acetate.
The transformation above can be performed with some reagent or combination of the reagents listed below. Give the necessary
reagents in the correct order, as a string of letters (without spaces or punctuation, such as "EBF"). If there is more than one correct
solution, provide just one answer.
A. 1)
D.
i
; 2) H3O
+ AICI 3
CI
G. NBS, heat
B. 1)
요.
'H
H
; 2) H3O+
Ei
E.
H. 1) LiAlH4; 2) H3O+
CI
+ pyridine
C. 1)
F. Mg
i
I. Br2, AlBr3
2) H3O+
A girl must convert 1-butyne into 2-pentanione. Assist her by recommending a synthetic plan to follow in order to obtain the desired result. Indicate all of the reagents she'll require.
Chapter 9 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...
Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Prob. 9.18PCh. 9.3 - Prob. 9.19PCh. 9.3 - Prob. 9.20PCh. 9.3 - Prob. 9.21PCh. 9.3 - Prob. 9.22PCh. 9.4 - Prob. 9.24PCh. 9.4 - Prob. 9.25PCh. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...
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- Show clearly how a retrosynthetic approach may be used to devise the synthesis of the compound shown below from commercially available precursors. Your answer should include a complete retrosynthetic analysis, reagents and reaction conditions. OHarrow_forwardPropose a synthetic route to convert the starting material shown below into the indicated target molecule. You may also use any stable molecule with three or fewer carbons and any commercially available reagents. You must show how to generate any organometallic reagents you use. Please show all reagents and intermediates in your synthesis. You do not need to show a reaction mechanism. OH youarrow_forward5) Show a reasonable synthesis for the following reaction. The reaction can be completed in 3 steps. Draw a reasonable (and complete) mechanism for the first transformation and the last transformation. Name the type of reactions for each step. HO OH OH CHOarrow_forward
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