Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Textbook Question
Chapter 9.3, Problem 9.12P
Suggest an efficient synthesis for each of the following transformations.
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2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
Reagents:
H₂O (B);
CH3CO₂H (D)
NaHCO3 (4); Hg(OAc)2 (5);
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
H₂O₂ / HO- (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
OH
-
α-α
Br
+ enant
Solvent Reagent(s) Solvent Reagent(s)
Based on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water?
Group of answer choices
MgO
BeO
CaO
BaO
From an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal?
Group of answer choices
Water coordination to the ions followed by sublimation into the gas phase
Sublimation of the crystal into gas-phase ions followed by water coordination to the ions
Ion dissociation from the crystal followed by water coordination to the ions
Water coordination to the ions followed by ion dissociation from the crystal
Chapter 9 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify how you would use a Gabriel synthesis to...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.2 - Identify whether each of the following compounds...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...
Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Suggest an efficient synthesis for each of the...Ch. 9.3 - Prob. 9.18PCh. 9.3 - Prob. 9.19PCh. 9.3 - Prob. 9.20PCh. 9.3 - Prob. 9.21PCh. 9.3 - Prob. 9.22PCh. 9.4 - Prob. 9.24PCh. 9.4 - Prob. 9.25PCh. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.5 - Predict the major product for each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...Ch. 9.6 - What reagents would you use to achieve each of the...
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- For which Group 2 metal (M), is this process the most exothermic? M2+(g) + O2−(g) + CO2(g) → MO(s) + CO2(g) Group of answer choices M = Sr M = Mg M = Ca M = Baarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); R₂BH (6); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI Solvent Reagent(s) Solvent Reagent(s) HO OHarrow_forwardFor which of the following ionic compounds would you expect the smallest difference between its theoretical and experimental lattice enthalpies? (You may assume these all have the same unit cell structure.) Electronegativities: Ca (1.0), Fe (1.8), Mg (1.2), O (3.5), S (2.5), Zn (1.6) Group of answer choices ZnO MgS CaO FeSarrow_forward
- In the Born-Haber cycle for KCl crystal formation, what enthalpy component must be divided by two? Group of answer choices KCl(s) enthalpy of formation Ionization energy for K(g) K(s) sublimation enthalpy Cl2 bond dissociation enthalpyarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O₂ / HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI хот Br Solvent Reagent(s) Solvent Reagent(s)arrow_forwardWhat is the correct chemical equation for the lattice formation reaction for CaBr2? Group of answer choices Ca2+(g) + 2 Br−(g) → CaBr2(s) ½ Ca2+(g) + Br−(g) → ½ CaBr2(s) Ca(s) + Br2(l) → CaBr2(s) Ca(s) + 2 Br−(g) → CaBr2(s)arrow_forward
- PLEASE ANSWER THE QUESTION!!!arrow_forward3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomerarrow_forwardcurved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism stepsarrow_forward
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