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General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 9.47PP
Calculate the [H3O+] for each of the following measurements of pH:
- a. drain cleaner, pH 12.10
- b. coffee, pH 5.5
- c. gastric juice, pH 2.00
- d. toothpaste, pH 8.3
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
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100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
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100
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140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
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33.5
119.0
36
133 0
1.2
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2.1
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Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
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4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 9 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 9 - Prob. 9.1PPCh. 9 - Indicate if each of the following statements is...Ch. 9 - Prob. 9.3PPCh. 9 - Prob. 9.4PPCh. 9 - Prob. 9.5PPCh. 9 - In each of the following equations, identify the...Ch. 9 - Prob. 9.7PPCh. 9 - Prob. 9.8PPCh. 9 - Prob. 9.9PPCh. 9 - Which of the following are strong bases? a....
Ch. 9 - Prob. 9.11PPCh. 9 - Prob. 9.12PPCh. 9 - Prob. 9.13PPCh. 9 - Prob. 9.14PPCh. 9 - Complete and balance the following neutralization...Ch. 9 - Complete and balance the following neutralization...Ch. 9 - Prob. 9.17PPCh. 9 - Complete and balance the following neutralization...Ch. 9 - Prob. 9.19PPCh. 9 - Prob. 9.20PPCh. 9 - Write an equilibrium constant expression lor the...Ch. 9 - Prob. 9.22PPCh. 9 - Prob. 9.23PPCh. 9 - Prob. 9.24PPCh. 9 - Prob. 9.25PPCh. 9 - Sulfur trioxide is produced by reacting sulfur...Ch. 9 - Prob. 9.27PPCh. 9 - Prob. 9.28PPCh. 9 - Prob. 9.29PPCh. 9 - When you exercise, energy is produced by...Ch. 9 - Using Tables 9.1 and 9.6, identity the stronger...Ch. 9 - Using Tables 9.1 and 9.6, identify the stronger...Ch. 9 - Prob. 9.33PPCh. 9 - Identify the acid and base on the reactant side of...Ch. 9 - Prob. 9.35PPCh. 9 - Prob. 9.36PPCh. 9 - Prob. 9.37PPCh. 9 - Write the formula and name of the conjugate acid...Ch. 9 - Complete the following reactions and identify the...Ch. 9 - Complete the following reactions and identify the...Ch. 9 - State if each of the following solutions is...Ch. 9 - State if each of the following solutions is...Ch. 9 - State if each of these following solutions is...Ch. 9 - Slate if each of the following solutions is...Ch. 9 - Calculate the pH of each of the solutions in...Ch. 9 - Calculate the pH of each of the solutions in...Ch. 9 - Calculate the [H3O+] for each of the following...Ch. 9 - Calculate the [H3O+J lor each of the following...Ch. 9 - Prob. 9.49PPCh. 9 - Using Table 9.8, determine the stronger acid from...Ch. 9 - Prob. 9.51PPCh. 9 - Prob. 9.52PPCh. 9 - Prob. 9.53PPCh. 9 - Prob. 9.54PPCh. 9 - Valine has the zwitterion structure shown in the...Ch. 9 - Glycine has the zwitterion structure shown in the...Ch. 9 - Prob. 9.57PPCh. 9 - Prob. 9.58PPCh. 9 - During stress or trauma, a person can start to...Ch. 9 - A person who overdoses on antacids may neutralize...Ch. 9 - Prob. 9.61APCh. 9 - Prob. 9.62APCh. 9 - Prob. 9.63APCh. 9 - What are some ingredients found in antacids? What...Ch. 9 - Prob. 9.65APCh. 9 - Prob. 9.66APCh. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - For the following reaction, 2HI(g)H2(g)+I2(g) a....Ch. 9 - Prob. 9.70APCh. 9 - Prob. 9.71APCh. 9 - Prob. 9.72APCh. 9 - Prob. 9.73APCh. 9 - Prob. 9.74APCh. 9 - Prob. 9.75APCh. 9 - Prob. 9.76APCh. 9 - Determine the pH for the following solutions....Ch. 9 - Determine the pi! for the following solutions....Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Consider the acetic-acid buffer system with acetic...Ch. 9 - Consider the lactic-acid buffer with lactic acid,...Ch. 9 - In blood plasma, pH is maintained by the carbonic...Ch. 9 - Adding a few drops o! a strong add to water will...Ch. 9 - Consider the amino acid valine shown in its...Ch. 9 - Prob. 9.86CPCh. 9 - Prob. 9.87CPCh. 9 - Prob. 9.88CPCh. 9 - Prob. 9.89CPCh. 9 - Naproxen, the active ingredient in Aleve has the...Ch. 9 - To determine the concentration of an unknown weak...Ch. 9 - Explain why the following amino acid cannot exist...Ch. 9 - Prob. 1IA.1QCh. 9 - Prob. 1IA.2QCh. 9 - Prob. 1IA.3QCh. 9 - Prob. 1IA.4QCh. 9 - Prob. 1IA.5QCh. 9 - Provide the a. conjugate base of H2S. _______ b....Ch. 9 - If the lungs fail to expel normal amounts of CO2...Ch. 9 - If the lungs expel CO2 faster than normally...Ch. 9 - Prob. 2IA.3QCh. 9 - Prob. 2IA.4QCh. 9 - Prob. 1ICCh. 9 - Prob. 2ICCh. 9 - Prob. 3IC
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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