Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 9, Problem 9.39E
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Research in surface science is carried out using stainless steel ultra-high vacuum chambers with pressures as low as 10-12 torr. How many molecules are there in a 1.00 cm3 volume at this pressure and at a temperature of 300 K? For comparison, calculate the number of molecules in a 1.00 cm3 volume at atmospheric pressure and room temperature. In outer space the pressure is approximately 1.3 x 10-11 Pa and the temperature is approximately 2.7 K (determined using the blackbody radiation of the universe). How many molecules would you expect find in 1.00 cm3 of outer space?
Draw the predominant form of
arginine at pH = 7.9. The pKa of the
side chain is 12.5. Include proper
stereochemistry.
H2N
OH
NH
H₂N
'N'
છ
H
pH = 7.9
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Chapter 9 Solutions
Physical Chemistry
Ch. 9 - For an object having mass m falling in the z...Ch. 9 - For the system in exercise 9.1, determine the...Ch. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - List some unexplainable phenomena from the...Ch. 9 - Draw, label, and explain the functions of the...Ch. 9 - Convert a a wavelength of 218A to cm1, b a...Ch. 9 - Prob. 9.9ECh. 9 - Prob. 9.10E
Ch. 9 - Explain why no lines in the Balmer series of the...Ch. 9 - What are the series limits see the previous...Ch. 9 - The following are the numbers n2 for some of the...Ch. 9 - The Balmer series is isolated from the other...Ch. 9 - Given that the wavelengths of the first three...Ch. 9 - Some scientists study Rydberg atoms, atoms whose...Ch. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - a How much radiant energy is given off, in...Ch. 9 - Stefans law, equation 9.18, suggests that any body...Ch. 9 - Prob. 9.21ECh. 9 - Betelgeuse pronounced beetle juice is a reddish...Ch. 9 - An average human body has a surface area of...Ch. 9 - Prob. 9.24ECh. 9 - The slope of the plot of energy versus wavelength...Ch. 9 - a Use Wien displacement law to determine the max...Ch. 9 - Prob. 9.27ECh. 9 - Sunburn is caused by ultraviolet UV radiation. Why...Ch. 9 - Calculate the energy of photon having: a a...Ch. 9 - Prob. 9.30ECh. 9 - Integrate Plancks law equation 9.23 from the...Ch. 9 - Calculate the power of light in the wavelength...Ch. 9 - Prob. 9.33ECh. 9 - Work functions are typically given in units of...Ch. 9 - Determine the speed of an electron being emitted...Ch. 9 - Lithium has a work function of 2.90eV. Light...Ch. 9 - Prob. 9.37ECh. 9 - Assume that an electron can absorb more than one...Ch. 9 - The photoelectric effect is used today to make...Ch. 9 - Prob. 9.40ECh. 9 - Prob. 9.41ECh. 9 - Prob. 9.42ECh. 9 - Prob. 9.43ECh. 9 - Prob. 9.44ECh. 9 - Use equation 9.34 to determine the radii, in...Ch. 9 - Prob. 9.46ECh. 9 - Calculate the energies of an electron in the...Ch. 9 - Prob. 9.48ECh. 9 - Show that the collection of constants given in...Ch. 9 - Prob. 9.50ECh. 9 - Equations 9.33 and 9.34 can be combined and...Ch. 9 - a Compare equations 9.31, 9.34, and 9.41 and...Ch. 9 - Label each of the properties of an electron as a...Ch. 9 - The de Broglie equation for a particle can be...Ch. 9 - What is the wavelength of a baseball having mass...Ch. 9 - Electron microscopes operate on the fact that...Ch. 9 - Prob. 9.57ECh. 9 - Prob. 9.58ECh. 9 - Determine under what conditions of temperature and...Ch. 9 - Prob. 9.60ECh. 9 - Prob. 9.61E
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- 142. A mixture of H2(g) and N2(g) has a density of 0.216 g/liter at 300 K and 500 torr. What is the mole fraction composition of the mixture?arrow_forwardOne liter of N2(g) at 2.1 bar and two liters of Ar(g) at 3.4 bar are mixed in a 4.0 liter flask to form an ideal gas mixture. Calculate the value of the final pressure of the mixture if the initial and final temperature of the gases are the same. Repeat this calculation if the initial temperature of the N2(g) and Ar(g) are 304 K and 402 K, respectively, and the final temperature of the mixture is 377 K.arrow_forward10 5 4. These four 'H NMR spectra were recorded from different isomers with molecular formula CsH,CIO. They all contain a carbonyl group. Determine the structure of the different isomers. 0 10 5 0 10 5 10 9 8 7 6 5 4 3. 1 0 9 10 10 66 9 0 10 9 10 5 1 8 7 6 5 3 2 -a 8 7 6 5 1 10 9 8 7 6 5 22 2 1 0 3 2 16 1 0 3 2 1 2 6 0arrow_forward
- Use the expression below to ⚫ calculate its value and report it to the proper number of significant digits (you may need to round your answer). ⚫ calculate the % error (or % relative error or % inherent error) ⚫ calculate the absolute error. (20.54±0.02 × 0.254±0.003) / (3.21±0.05) = Value: % Error: Absolute error: ± | % (only 1 significant digit) (only 1 significant digit)arrow_forwardIn each case (more ductile, more brittle, more tough or resistant), indicate which parameter has a larger value. parameter Elastic limit Tensile strength more ductile Strain at break Strength Elastic modulus more fragile more tough or resistantarrow_forwardNonearrow_forward
- What functional groups are present in this IRarrow_forwardIn each case (more ductile, more brittle, more tough or resistant), indicate which parameter has a larger value. parameter Elastic limit Tensile strength more ductile Strain at break Strength Elastic modulus more fragile more tough or resistantarrow_forward4) A typical bottle of pop holds carbon dioxide at a pressure of 5 atm. What is the concentration of carbon dioxide in th solution? 5) A stream flowing over rocks and such is exposed to the atmosphere and well aerated. What would be the nitrogen concentration in the water at 25°C? (Air pressure is 1.000 bar.)arrow_forward
- Use the expression below to ⚫ calculate its value and report it to the proper number of significant digits (you may need to round your answer). ⚫ calculate the % error (or % relative error or % inherent error) ⚫ calculate the absolute error. (30.078±0.003) - (20.174±0.001) + (9.813±0.005) = Value: % Error: absolute error: ± % (only 1 significant digit) (only 1 significant digit)arrow_forwardDon't used Ai solution and don't used hand raitingarrow_forwardCircle the letter next to the most appropriate response. 1) Which is likely to be the least soluble with water? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 2) Which is likely to be the most soluble in 3,4-dimethyloctane? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 3) When ammonium nitrate is dissolved in water, the solution: a) gets warmer. b) gets colder. c) stays the same temperature. d) is none of the above because potassium nitrate is insoluble.arrow_forward
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