The structural formula for the haloalkane that forms given alkene has to be given. Concept Introduction: Elimination: An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction. In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction. The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate. E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Question

On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 min

Answer 1

Question

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

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On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 min

d. In Figure 4, each stationary phase shows some negative correlation between plate count and retention factor. In other words, as k' increases, N decreases. Explain this relationship between k' and N. Plate Count (N) 4000 3500 2500 2000 1500 1000 Figure 4. Column efficiency (N) vs retention factor (k') for 22 nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000 Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain k' less than 15, which was achieved for most solutes as follows: FMS (30/70 A/W), PGC (60/40), COZ (80/20). Slightly different compositions were used for the most highly retained solutes. All columns were 50 mm × 4.6 mm id and packed with 5 um particles, except for COZ, which was packed with 3 um particles. All other chromatographic conditions were constant: column length 5 cm, column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C, and injection volume 0.5 μL Log(k'x/K'ethylbenzene) FMS 1.5 1.0 0.5 0.0 ཐྭ ཋ ཤྩ བྷྲ ; 500 0 5 10…

f. Predict how the van Deemter curve in Figure 7 would change if the temperature were raised from 40 °C to 55 °C. Figure 7. van Desmter curves in reduced coordinates for four nitroalkane homologues (nitropropane, black; nitrobutane, red; nitropentane, blue; and nitrohexane, green) separated on the FMS phase. Chromatographic conditions: column dimensions 50 mm × 4.6 mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection volume 0.5 and column temperature 40 °C. No corrections to the plate heights have been made to account for extracolumn dispersion. Reduced Plate Height (h) ° 20 40 60 Reduced Velocity (v) 8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and standard are spiked with a fixed amount of toluene as an internal standard. The following data are obtained: Ppb benzene Peak area benzene Peak area toluene 10.0 252 376 Sample 533 368 What is the concentration of benzene in the sample?

Answer 2

Question

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

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Answer 3

Question

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

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Answer 4

Question

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

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Answer 5

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 6

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 7

Chapter 9, Problem 9.38P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structural formula for the halo alkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 14

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 15

(e)

Interpretation Introduction

Interpretation:

The structural formula for the haloalkane that forms given alkene has to be given.

Concept Introduction:

Elimination:

An atom or group are removed from saturated compound to give unsaturated alkene is known as elimination reaction.

In elimination, the removal of halogen ion forms a carbocation followed by removal of hydrogen ion forms an alkene is known as E1 reaction.

The abstraction of proton and removal of leaving group takes simultaneously means it is E2 reaction because the rate of reaction depends on both base and substrate.

E1 elimination fallows saytzeff rule (more substituted alkene is formed).

Answer 16

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Answer 27

Ch. 9.1 - Prob. 9.1P Ch. 9.3 - Prob. 9.2P Ch. 9.3 - Prob. 9.3P Ch. 9.3 - Prob. 9.4P Ch. 9.4 - Prob. 9.5P Ch. 9.5 - Predict the -elimination product(s) formed when...Ch. 9.7 - Prob. 9.7P Ch. 9.9 - Predict whether each reaction proceeds...Ch. 9.9 - Prob. AQ Ch. 9.9 - Prob. BQ

Solution Summary: The author explains the structural formula for the halo alkane that forms given alkene.

Chapter 9 Solutions