(a) Interpretation: The products of the reaction between 1 - bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 1

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 3

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 4

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 5

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 6

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 7

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the products of the reaction between 1- bromobutane and sodium methoxide are to be predicted.

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