The alcoholic group, OH and halogen group present in the given synthetic steroid, dexamethasone are to classified as 1 ° , 2 ° , or 3 ° . Concept introduction: The alkyl halide and alcohol are identified as primary ( 1 ° ) , secondary ( 2 ° ) and tertiary, ( 3 ° ) . The primary alkyl halide or alcohol is the one in which a halide group or OH group is attached to that carbon atom which is bonded with one carbon atom only. The secondary alkyl halide or alcohol is the one in which a halide group or OH group is attached to that carbon atom which is bonded with two carbon atoms. The tertiary alkyl halide or alcohol is the one in which halide group or OH group is attached to that carbon atom which is bonded with three carbon atoms.
The alcoholic group, OH and halogen group present in the given synthetic steroid, dexamethasone are to classified as 1 ° , 2 ° , or 3 ° . Concept introduction: The alkyl halide and alcohol are identified as primary ( 1 ° ) , secondary ( 2 ° ) and tertiary, ( 3 ° ) . The primary alkyl halide or alcohol is the one in which a halide group or OH group is attached to that carbon atom which is bonded with one carbon atom only. The secondary alkyl halide or alcohol is the one in which a halide group or OH group is attached to that carbon atom which is bonded with two carbon atoms. The tertiary alkyl halide or alcohol is the one in which halide group or OH group is attached to that carbon atom which is bonded with three carbon atoms.
Solution Summary: The author explains the classification of alcoholic group, OH and halogen group present in the given synthetic steroid, dexamethasone.
Definition Definition Organic compounds in which one or more hydrogen atom in an alkane is replaced by a halogen atom (fluorine, chlorine, bromine, or iodine). These are also known as haloalkanes.
Chapter 9, Problem 9.2P
Interpretation Introduction
Interpretation: The alcoholic group, OH and halogen group present in the given synthetic steroid, dexamethasone are to classified as 1°, 2°, or 3°.
Concept introduction: The alkyl halide and alcohol are identified as primary (1°), secondary (2°) and tertiary, (3°). The primary alkyl halide or alcohol is the one in which a halide group or OH group is attached to that carbon atom which is bonded with one carbon atom only. The secondary alkyl halide or alcohol is the one in which a halide group or OH group is attached to that carbon atom which is bonded with two carbon atoms. The tertiary alkyl halide or alcohol is the one in which halide group or OH group is attached to that carbon atom which is bonded with three carbon atoms.
Q3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles
Considering the following reactions:
a) Predict the products to complete the reactions.
b) Use curved electron-pushing arrows to show the mechanism for the reaction in
the forward direction. Redraw some of the compounds to explicitly illustrate all
bonds that are broken and all bonds that are formed.
c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions.
A.
S
+
AICI 3
B.
+
H₂O
3. A thermometer is placed in a test tube of chipped ice at -5.0 °C. The temperature is recorded at the
time intervals shown below until room temperature is reached. Plot the data given below on graph
paper and explain all flat, horizontal portions of the curve. Plot time on the X-axis!
Time (min)
Temperature (°C)
0
-5.0
2
-2.5
4
-1.0
6
0.0
10
0.0
15
0.0
20
0.0
25
0.0
30
1.5
35
4.0
40
8.0
45
11.5
50
15.0
55
17.5
60
19.0
65
20.0
70
20.0
75
20.0
80
20.0
Naming the Alkanes
a) Write the IUPAC nomenclature of the compound below
b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and
quaternary carbons.
c) Rank pentane, neopentane and isopentane for boiling point.
pentane:
H3C-CH2-CH2-CH2-CH3
neopentane:
CH3
H3C-Ċ-CH3
I
CH3
isopentane:
CH3
H3C-CH2-CH-CH3