(a) Interpretation: An explanation for the formation of more stable carbocation by 1 , 2 -shift of given intermediate is to be stated. Concept introduction: A less stable carbocation undergoes 1, 2-shift , (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 1

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. + HBr

2. Draw all possible products (regardless of major/minor) from the following reaction. No need to show any curly-arrow mechanism. No need to label major or minor product. H2 MeOH C. CH3 Br

Answer 2

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 3

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 4

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 5

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 6

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 7

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 8

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 9

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 10

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 11

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 9 - Draw all constitutional isomers having molecular...Ch. 9 - Prob. 9.2P Ch. 9 - Give the IUPAC name for each compound.Ch. 9 - Problem 9.3 Give the structure corresponding to...Ch. 9 - Prob. 9.5P Ch. 9 - Name CH33COCH3, a gasoline additive commonly...Ch. 9 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9 - Problem 9.6 Rank the following compounds in order...Ch. 9 - Which mechanism is favored by the use of crown...Ch. 9 - Draw the organic product of each reaction.

Solution Summary: The author explains the formation of more stable carbocation by 1,2 -shift of given intermediate.

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