(a) Interpretation: An explanation for the formation of more stable carbocation by 1 , 2 -shift of given intermediate is to be stated. Concept introduction: A less stable carbocation undergoes 1, 2-shift , (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 1

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Assign all the protons

PROPOSE REACTION MECHANISM FOR ACID-CATALYZED REACTION OF 3-PENTANONE WITH DIMETHYLAMINE

Answer 2

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 3

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 4

Question

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

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Answer 5

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 6

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 7

Chapter 9, Problem 9.17P

Interpretation Introduction

(a)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 8

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 9

Interpretation Introduction

(b)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 10

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 11

Interpretation Introduction

(c)

Interpretation: An explanation for the formation of more stable carbocation by 1,2-shift of given intermediate is to be stated.

Concept introduction: A less stable carbocation undergoes 1, 2-shift, (migration of an alkyl group or hydrogen atom from one carbon to an adjacent carbon atom) and gives more stable carbocation.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9 - Draw all constitutional isomers having molecular...Ch. 9 - Prob. 9.2P Ch. 9 - Give the IUPAC name for each compound.Ch. 9 - Problem 9.3 Give the structure corresponding to...Ch. 9 - Prob. 9.5P Ch. 9 - Name CH33COCH3, a gasoline additive commonly...Ch. 9 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9 - Problem 9.6 Rank the following compounds in order...Ch. 9 - Which mechanism is favored by the use of crown...Ch. 9 - Draw the organic product of each reaction.

Solution Summary: The author explains the formation of more stable carbocation by 1,2 -shift of given intermediate.

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