(a) Interpretation: A graph should be plotted using the spreadsheet for given information. Concept introduction: Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Question

1d. Use Le Chatelier's principle to describe the effect of the following changes on the position of the Haber-Bosch equilibrium: N2(g) + 3H2(g)= 2NH3(9) AH = -92kJ Choose one of the following answers: shift to reactant side, shift to product side or no change and draw the resulting graph. I. Increase the [N2(g)] Effect: H₂ N₂ NH3 II. Decrease the volume of the container. Effect: H₂ N₂2 NH3

Answer 1

Question

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

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1d. Use Le Chatelier's principle to describe the effect of the following changes on the position of the Haber-Bosch equilibrium: N2(g) + 3H2(g)= 2NH3(9) AH = -92kJ Choose one of the following answers: shift to reactant side, shift to product side or no change and draw the resulting graph. I. Increase the [N2(g)] Effect: H₂ N₂ NH3 II. Decrease the volume of the container. Effect: H₂ N₂2 NH3

f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? CH2 1.60Å H₂C * H₂C CH2 C H2C * C Of H₂ 120°

e) Determine the hybridization and geometry around the indicated carbon atoms. H3C CH3 B HC CH2 A C C C CH3

Answer 2

Question

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

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Answer 3

Question

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

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Answer 4

Question

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

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Answer 5

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 6

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 7

Chapter 9, Problem 9.21QAP

Interpretation Introduction

(a)

Interpretation:

A graph should be plotted using the spreadsheet for given information.

Concept introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The least square equation for the given data should be determined.

Concept introduction:

Flame emission spectrography is named so, because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The statistics of the line plotted in option b should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The percentage of Na₂O in each given sample and the absolute and relative standard deviations should be determined.

Introduction:

Flame emission spectrography is so named because the atoms are exposed to a flame to get the required amount of energy of excitation. This is a classical method and has been widely replaced by the plasma spectroscopies.

Answer 14

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Ch. 9 - Prob. 9.1QAP Ch. 9 - Prob. 9.2QAP Ch. 9 - Why is an electrothermal atomizer more sensitive...Ch. 9 - Prob. 9.4QAP Ch. 9 - Prob. 9.5QAP Ch. 9 - Prob. 9.6QAP Ch. 9 - Prob. 9.7QAP Ch. 9 - Prob. 9.8QAP Ch. 9 - Prob. 9.9QAP Ch. 9 - Prob. 9.10QAP

Chapter 9 Solutions