Water gas is the name for the mixture of CO and H 2 prepared by reaction of steam with carbon at 1000°C: C ( s ) +H 2 O ( g ) → CO ( g ) +H 2 ( g ) "Water gas" The hydrogen is then purified and used as a starting material for preparing ammonia. Use the following information to calculate Δ H ° in kilojoules for the water-gas reaction: C ( s ) + O 2 ( g ) → C O 2 ( g ) Δ H ° = − 3 93 .5 kJ 2 C O ( g ) + O 2 ( g ) → 2 C O 2 ( g ) Δ H ° = − 566. 0 kJ 2 H 2 ( g ) + O 2 ( g ) → 2 H 2 O ( g ) Δ H ° = − 48 3 .6 kJ
Water gas is the name for the mixture of CO and H 2 prepared by reaction of steam with carbon at 1000°C: C ( s ) +H 2 O ( g ) → CO ( g ) +H 2 ( g ) "Water gas" The hydrogen is then purified and used as a starting material for preparing ammonia. Use the following information to calculate Δ H ° in kilojoules for the water-gas reaction: C ( s ) + O 2 ( g ) → C O 2 ( g ) Δ H ° = − 3 93 .5 kJ 2 C O ( g ) + O 2 ( g ) → 2 C O 2 ( g ) Δ H ° = − 566. 0 kJ 2 H 2 ( g ) + O 2 ( g ) → 2 H 2 O ( g ) Δ H ° = − 48 3 .6 kJ
Solution Summary: The author explains how the value of DeltaHo in kJ for a water-gas reaction can be determined by adding the reactions of steps of the mechanism.
Water gas is the name for the mixture of CO and
H
2
prepared by reaction of steam with carbon at
1000°C:
C
(
s
)
+H
2
O
(
g
)
→
CO
(
g
)
+H
2
(
g
)
"Water gas" The hydrogen is then purified and used as a starting material for preparing ammonia. Use the following information to calculate
Δ
H
°
in kilojoules for the water-gas reaction:
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
Δ
H
°
=
−
3
93
.5 kJ
2
C
O
(
g
)
+
O
2
(
g
)
→
2
C
O
2
(
g
)
Δ
H
°
=
−
566.
0 kJ
2
H
2
(
g
)
+
O
2
(
g
)
→
2
H
2
O
(
g
)
Δ
H
°
=
−
48
3
.6 kJ
"Water gas" is an industrial fuel composed of a mixture of carbon monoxide and hydrogen gases. When this
fuel is burned, carbon dioxide and water result. From the information given below, write a balanced equation
and determine the enthalpy of this reaction:
CO(g) + O2(g) → CO₂(g) + 282.8 kJ
H2(g) + O2(g) → H₂O(g) + 241.8 kJ
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4. Calculate AG for the following reaction at 25°C. Will the reaction occur (be spontaneous)? How do you
know?
NH3(g) + HCl(g) → NH4Cl(s)
AH=-176.0 kJ
AS-284.8 J-K-1
true or false
The equilibrium constant for this reaction is 0.20.
N2O4(g) ⇔ 2NO2(g)
Based on the above, the equilibrium constant for the following reaction is 5.
4NO2(g) ⇔ 2N2O4(g)
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