Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
9th Edition
ISBN: 9781305968707
Author: Spencer L. Seager
Publisher: Brooks Cole
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Chapter 9, Problem 9.108E
Predict the relative pH (greater than
a. Sodium hypochlorite,
b. Sodium formate,
c. Potassium nitrate,
d. Sodium phosphate,
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Calculate the change in pH that occurs when 1.0 g NaOH is added to 250 mL of each of the following solutions.a. Pure water b. 0.0200 M NH3 c. 0.100 M NaOHd. 0.250 M HCL
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18
Calculate the H* ion concentration in a 7.8 x 1o M Ca(OH)2 solution.
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The Ka of an acid is known to be 1.51 X 10^-5. A solution is made by adding 0.279 mol of the acid to enough water to make the final volume 1.30 L.
a. what is the equilibrium concentration of H_3O+
b. what is the equilibrium pH of the solution
c. what is the equilibrium concentration of the conjugate base
d. what is the equilibruim concentration of the acid
e. what is the % dissociation of the acid
Chapter 9 Solutions
Chemistry For Today: General, Organic, And Biochemistry, Loose-leaf Version
Ch. 9 - Write the dissociation equations for the following...Ch. 9 - Write the dissociation equations for the following...Ch. 9 - Each of the following produces a basic solution...Ch. 9 - Prob. 9.4ECh. 9 - Identify each Brnsted acid and base in the...Ch. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Write equations to represent the Brnsted acid...
Ch. 9 - Write a formula for the conjugate base formed when...Ch. 9 - Write a formula for the conjugate base formed when...Ch. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - The following reactions illustrate Brnsted...Ch. 9 - Prob. 9.16ECh. 9 - Write equations to illustrate the acid-base...Ch. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.22ECh. 9 - The acid H3C6H5O7 forms the citrate ion, C6H5O73,...Ch. 9 - The acid H2C4H4O4 forms the succinate ion,...Ch. 9 - Prob. 9.25ECh. 9 - Prob. 9.26ECh. 9 - Calculate the molar concentration of OH in water...Ch. 9 - Calculate the molar concentration of OH in water...Ch. 9 - Calculate the molar concentration of H3O+ in water...Ch. 9 - Prob. 9.30ECh. 9 - Classify the solutions represented in Exercises...Ch. 9 - Classify the solutions represented in Exercises...Ch. 9 - Prob. 9.33ECh. 9 - Prob. 9.34ECh. 9 - Determine the pH of water solutions with the...Ch. 9 - Prob. 9.36ECh. 9 - Prob. 9.37ECh. 9 - Determine the pH of water solutions with the...Ch. 9 - Determine the [H+] value for solutions with the...Ch. 9 - Determine the [H+] value for solutions with the...Ch. 9 - Prob. 9.41ECh. 9 - Prob. 9.42ECh. 9 - The pH values listed in Table 9.1 are generally...Ch. 9 - Prob. 9.44ECh. 9 - Prob. 9.45ECh. 9 - Prob. 9.46ECh. 9 - Prob. 9.47ECh. 9 - Using the information in Table 9.4, describe how...Ch. 9 - Write balanced molecular equations to illustrate...Ch. 9 - Write balanced molecular equations to illustrate...Ch. 9 - Prob. 9.51ECh. 9 - Prob. 9.52ECh. 9 - Prob. 9.53ECh. 9 - Prob. 9.54ECh. 9 - Write balanced molecular, total ionic, and net...Ch. 9 - Prob. 9.56ECh. 9 - Prob. 9.57ECh. 9 - Prob. 9.58ECh. 9 - Prob. 9.59ECh. 9 - Prob. 9.60ECh. 9 - Prob. 9.61ECh. 9 - Prob. 9.62ECh. 9 - Prob. 9.63ECh. 9 - Prob. 9.64ECh. 9 - Prob. 9.65ECh. 9 - Prob. 9.66ECh. 9 - Prob. 9.67ECh. 9 - Prob. 9.68ECh. 9 - Prob. 9.69ECh. 9 - Prob. 9.70ECh. 9 - Determine the number of moles of each of the...Ch. 9 - Prob. 9.72ECh. 9 - Prob. 9.73ECh. 9 - Determine the number of equivalents and...Ch. 9 - Determine the number of equivalents and...Ch. 9 - Prob. 9.76ECh. 9 - Prob. 9.77ECh. 9 - Prob. 9.78ECh. 9 - Prob. 9.79ECh. 9 - The Ka values have been determined for four acids...Ch. 9 - Prob. 9.81ECh. 9 - Prob. 9.82ECh. 9 - Prob. 9.83ECh. 9 - Prob. 9.84ECh. 9 - Prob. 9.85ECh. 9 - Prob. 9.86ECh. 9 - Arsenic acid (H3AsO4) is a moderately weak...Ch. 9 - Explain the purpose of doing a titration.Ch. 9 - Prob. 9.89ECh. 9 - Prob. 9.90ECh. 9 - Prob. 9.91ECh. 9 - Prob. 9.92ECh. 9 - Prob. 9.93ECh. 9 - Prob. 9.94ECh. 9 - Prob. 9.95ECh. 9 - Prob. 9.96ECh. 9 - A 25.00-mL sample of gastric juice is titrated...Ch. 9 - A 25.00-mL sample of H2C2O4 solution required...Ch. 9 - Prob. 9.99ECh. 9 - Prob. 9.100ECh. 9 - The following acid solutions were titrated to the...Ch. 9 - The following acid solutions were titrated to the...Ch. 9 - Prob. 9.103ECh. 9 - Prob. 9.104ECh. 9 - Prob. 9.105ECh. 9 - Prob. 9.106ECh. 9 - Prob. 9.107ECh. 9 - Predict the relative pH greater than 7, less than...Ch. 9 - Prob. 9.109ECh. 9 - Explain why the hydrolysis of salts makes it...Ch. 9 - How would the pH values of equal molar solutions...Ch. 9 - Write equations similar to Equations 9.48 and 9.49...Ch. 9 - Prob. 9.113ECh. 9 - Prob. 9.114ECh. 9 - Prob. 9.115ECh. 9 - a.Calculate the pH of a buffer that is 0.1M in...Ch. 9 - Which of the following acids and its conjugate...Ch. 9 - Prob. 9.118ECh. 9 - Prob. 9.119ECh. 9 - What ratio concentrations of NaH2PO4 and Na2HPO4...Ch. 9 - Prob. 9.121ECh. 9 - Prob. 9.122ECh. 9 - Prob. 9.123ECh. 9 - Prob. 9.124ECh. 9 - Prob. 9.125ECh. 9 - Prob. 9.126ECh. 9 - Prob. 9.127ECh. 9 - Prob. 9.128ECh. 9 - Prob. 9.129ECh. 9 - Bottles of ketchup are routinely left on the...Ch. 9 - Prob. 9.131ECh. 9 - Prob. 9.132ECh. 9 - Prob. 9.133ECh. 9 - Prob. 9.134ECh. 9 - Prob. 9.135ECh. 9 - Prob. 9.136ECh. 9 - Prob. 9.137ECh. 9 - A base is a substance that dissociates in water...Ch. 9 - Prob. 9.139ECh. 9 - Prob. 9.140ECh. 9 - What is the formula of the hydronium ion? a.H+...Ch. 9 - Which of the following substances has a pH closest...Ch. 9 - Dissolving H2SO4 in water creates an acid solution...Ch. 9 - Prob. 9.144ECh. 9 - A common detergent has a pH of 11.0, so the...Ch. 9 - Prob. 9.146ECh. 9 - The pH of a blood sample is 7.40 at room...Ch. 9 - Prob. 9.148ECh. 9 - Prob. 9.149ECh. 9 - Prob. 9.150ECh. 9 - Prob. 9.151ECh. 9 - Which of the following compounds would be...Ch. 9 - A substance that functions to prevent rapid,...Ch. 9 - Which one of the following equations represents...Ch. 9 - Which reaction below demonstrates a neutralization...Ch. 9 - In titration of 40.0mL of 0.20MNaOH with 0.4MHCl,...Ch. 9 - When titrating 50mL of 0.2MHCl, what quantity of...
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- What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?arrow_forwardStrong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.arrow_forwardUse the same symbols as in Question 61 ( = anion, =OH) for the box below. (a) Fill in a similar box (representing one liter of the same solution) after 2 mol of H+ (2) have been added. Indicate whether the resulting solution is an acid, base, or buffer. (b) Follow the directions of part (a) for the resulting solution after 2 mol of OH- (2 ) have been added. (c) Follow the directions of part (a) for the resulting solution after 5 mol of OH- (5 ) have been added. (Hint: Write the equation for the reaction before you draw the results.)arrow_forward
- The pH of Mixtures of Acid, Base, and Salt Solutions a When 0.10 mol of the ionic solid NaX, where X is an unknown anion, is dissolved in enough water to make 1.0 L of solution, the pH of the solution is 9.12. When 0.10 mol of the ionic solid ACl, where A is an unknown cation, is dissolved in enough water to make 1.0 L of solution, the pH of the solution is 7.00. What would be the pH of 1.0 L of solution that contained 0.10 mol of AX? Be sure to document how you arrived at your answer. b In the AX solution prepared above, is there any OH present? If so, compare the [OH] in the solution to the [H3O+]. c From the information presented in part a, calculate Kb for the X(aq) anion and Ka for the conjugate acid of X(aq). d To 1.0 L of solution that contains 0.10 mol of AX, you add 0.025 mol of HCl. How will the pH of this solution compare to that of the solution that contained only NaX? Use chemical reactions as part of your explanation; you do not need to solve for a numerical answer. e Another 1.0 L sample of solution is prepared by mixing 0.10 mol of AX and 0.10 mol of HCl. The pH of the resulting solution is found to be 3.12. Explain why the pH of this solution is 3.12. f Finally, consider a different 1.0-L sample of solution that contains 0.10 mol of AX and 0.1 mol of NaOH. The pH of this solution is found to be 13.00. Explain why the pH of this solution is 13.00. g Some students mistakenly think that a solution that contains 0.10 mol of AX and 0.10 mol of HCl should have a pH of 1.00. Can you come up with a reason why students have this misconception? Write an approach that you would use to help these students understand what they are doing wrong.arrow_forwardA solution is prepared from 0.150 mol of formic acid and enough water to make 0.425 L of solution. a Determine the concentrations of H3O+ and HCOO in this solution. b Determine the H3O+ concentration that would be necessary to decrease the HCOO concentration above by a factor of 10. How many milliliters of 2.00 M HCl would be required to produce this solution? Consider that the solution was made by combining the HCl, the HCOOH, and enough water to make 0.425 L of solution. c Qualitatively, how can you account for the differences in the percentage dissociation of formic acid in parts a and b of this problem?arrow_forward. The concepts of acid-base equilibria were developed in this chapter for aqueous solutions (in aqueous solutions, water is the solvent and is intimately involved in the equilibria). However, the Brønsted-Lowry acid-base theory can be extended easily to other solvents. One such solvent that has been investigated in depth is liquid ammonia. NH3. a. Write a chemical equation indicating how HCl behaves as an acid in liquid ammonia. b. Write a chemical equation indicating how OH- behaves as a base in liquid ammonia.arrow_forward
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