Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product. Concept introduction: Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond ( alkene ). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule. Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene. To draw: the mechanism for given hydro halogenation reaction.

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Answer 1

Question

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

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First image: I have to explain why the molecule C is never formed in these conditions Second image: I have to propose a synthesis for the lactone A

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Answer 2

Question

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

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Answer 3

Question

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

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Answer 4

Question

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

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Answer 5

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

Answer 6

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

Answer 7

Chapter 9, Problem 69PP

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To draw: the mechanism for given hydro halogenation reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the region selectivity in product.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

To explain: The region selectivity of the product in the reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9.3 - Prob. 3PTS Ch. 9.3 - Prob. 4ATS Ch. 9.3 - Prob. 5ATS Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 7PTS Ch. 9.3 - Prob. 8ATS Ch. 9.3 - Prob. 9ATS Ch. 9.4 - Prob. 10CC Ch. 9.4 - Prob. 11CC Ch. 9.4 - Prob. 3LTS

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Chapter 9 Solutions