ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
Question
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Chapter 9, Problem 64PP

a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given reaction.

Concept introduction:

  • Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.
  • Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.
  • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.
  • Simple hydration in acidic media gives the addition product through carbocation intermediate.

To draw: the mechanism for the given reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given reaction.

Concept introduction:

  • Mechanism: mechanism describes the reaction path and process. In reaction mechanism, curved arrows are used to show the electron transfer from one group to another.
  • Curved arrow direction should be from lone pair electrons to electron deficient species such as carbocation etc.
  • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.
  • Simple hydration in acidic media gives the addition product through carbocation intermediate.

To draw: the mechanism for the given reaction.

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Chapter 9 Solutions

ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<

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