Reagents should be predicted for the given transformations. Concept introduction: Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below. Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base. Elimination of compound in presence of bulky base leads to less substituted alkene , in presence of strong base (not bulky) leads to more substituted alkene. Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound. Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways. Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate. Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction. Simple hydration in acidic media gives the addition product through carbocation intermediate. Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides. To find: the reagent for the given transformation.

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Answer 1

Question

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

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Commercial bleach contains either chlorine or oxygen as an active ingredient. A commercial oxygenated bleach is much safer to handle and less likely to ruin your clothes. It is possible to determine the amount of active ingredient in an oxygenated bleach product by performing a redox titration. The balance reaction for such a titration is: 6H+ +5H2O2 +2MnO4- à 5O2 + 2Mn2+ + 8H2O If you performed the following procedure: “First, dilute the Seventh Generation Non-Chlorine Bleach by pipetting 10 mL of bleach in a 100 mL volumetric flask and filling the flask to the mark with distilled water. Next, pipet 10 mL of the diluted bleach solution into a 250 mL Erlenmeyer flask and add 20 mL of 1.0 M H2SO4 to the flask. This solution should be titrated with 0.0100 M KMnO4 solution.” It took 18.47mL of the KMnO4 to reach the endpoint on average. What was the concentration of H2O2 in the original bleach solution in weight % assuming the density of bleach is 1g/mL?

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Answer 2

Question

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

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Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

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Answer 4

Question

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 6

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 7

Chapter 9, Problem 70PP

(a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 18

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 19

(g)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 20

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 21

(h)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 22

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 23

(i)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 24

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 25

(j)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 26

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 27

(k)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.

Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.

Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.

Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.

Hydration: addition of water molecule across the double bond is called hydration reaction. Hydration of alkene can be achieved in many ways.

Oxy mercuration-demercuration: this process undergoes through the addition of water according to Markovnikov’s rule without forming carbocation as intermediate.

Hydroboration-oxidation reaction: addition of –H and –OH group across the double bond in presence of borane and hydrogen peroxide with base is known as hydroboration-oxidation reaction.

Simple hydration in acidic media gives the addition product through carbocation intermediate.

Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

Answer 28

Expert Solution & Answer

Answer 29

Expert Solution & Answer

Answer 30

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Answer 31

Ch. 9.3 - Prob. 3PTS Ch. 9.3 - Prob. 4ATS Ch. 9.3 - Prob. 5ATS Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 7PTS Ch. 9.3 - Prob. 8ATS Ch. 9.3 - Prob. 9ATS Ch. 9.4 - Prob. 10CC Ch. 9.4 - Prob. 11CC Ch. 9.4 - Prob. 3LTS

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Chapter 9 Solutions