Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility. Concept introduction: Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond ( alkene ). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule. Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene. Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position. To draw: the mechanism for given hydro halogenation reaction.

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Answer 1

Question

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

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Answer 2

Question

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

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Answer 3

Question

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

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Answer 4

Question

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

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Answer 5

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

Answer 6

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

Answer 7

Chapter 9.3, Problem 5ATS

(a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To draw: the mechanism for given hydro halogenation reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given hydro halogenation reaction and needed to explain the product possibility.

Concept introduction:

Hydro halogenation reaction: In hydro halogenation reaction hydrogen halide added across the unsaturated bond (alkene). In this addition reaction chloride ion added to the most substituted carbon position of the alkene, which follows the Markovnikov’s rule.

Markovnikov’s rule: In addition reactions negatively addendum goes to most substituted carbon position in alkene.

Anti-Markovnikov’s product is possible if the carbocation is stabilized through strong electron donating group at less substituted carbon position.

To explain: The stability of the carbocation intermediate in reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9.3 - Prob. 3PTS Ch. 9.3 - Prob. 4ATS Ch. 9.3 - Prob. 5ATS Ch. 9.3 - Prob. 2LTS Ch. 9.3 - Prob. 7PTS Ch. 9.3 - Prob. 8ATS Ch. 9.3 - Prob. 9ATS Ch. 9.4 - Prob. 10CC Ch. 9.4 - Prob. 11CC Ch. 9.4 - Prob. 3LTS

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Chapter 9 Solutions