Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card

2nd Edition

ISBN: 9781305717633

Author: Steven S. Zumdahl, Susan A. Zumdahl

Publisher: Cengage Learning

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Crystal Lattices and Unit Cell

Consider a crystal. The regular and repeating pattern of constituent particles is the most distinguishing feature of crystalline solids. A crystal lattice is formed when these particles are replaced with representative points. The three-dimensional arran…

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Chapter 9, Problem 47E

X rays from a copper X-ray tube (λ = 154 pm) were diffracted at an angle of 14.22 degrees by a crystal of silicon. Assuming first-order diffraction (n = 1 in the Bragg equation), what is the interplanar spacing in silicon?

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Chapter 9, Problem 46E

Chapter 9, Problem 48E

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Chapter 9 Solutions

Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card

Ch. 9 - What are intermolecular forces? How do they differ...Ch. 9 - Define the following terms and describe how each...Ch. 9 - Compare and contrast solids, liquids, and gases.Ch. 9 - Prob. 4RQ Ch. 9 - What is a lattice? What is a unit cell? Describe a...Ch. 9 - What is closest packing? What is the difference...Ch. 9 - Describe, in general, the structures of ionic...Ch. 9 - Prob. 9RQ Ch. 9 - Prob. 10RQ Ch. 9 - Compare and contrast the phase diagrams of water...

Ch. 9 - It is possible to balance a paper clip on the...Ch. 9 - Prob. 2ALQ Ch. 9 - Prob. 3ALQ Ch. 9 - Prob. 4ALQ Ch. 9 - Prob. 5ALQ Ch. 9 - Prob. 6ALQ Ch. 9 - Prob. 7ALQ Ch. 9 - Prob. 8ALQ Ch. 9 - Prob. 9ALQ Ch. 9 - Prob. 10ALQ Ch. 9 - Prob. 11ALQ Ch. 9 - Prob. 12Q Ch. 9 - In the diagram below, which lines represent the...Ch. 9 - Prob. 14Q Ch. 9 - Atoms are assumed to touch in closest packed...Ch. 9 - Define critical temperature and critical pressure....Ch. 9 - Prob. 17Q Ch. 9 - Prob. 18Q Ch. 9 - Prob. 19Q Ch. 9 - Prob. 20Q Ch. 9 - Prob. 21Q Ch. 9 - A common response to hearing that the temperature...Ch. 9 - Prob. 23Q Ch. 9 - Prob. 24Q Ch. 9 - When wet laundry is hung on a clothesline on a...Ch. 9 - Cake mixes and other packaged foods that require...Ch. 9 - You have three covalent compounds with three very...Ch. 9 - Prob. 28Q Ch. 9 - Compare and contrast the structures of the...Ch. 9 - Prob. 30Q Ch. 9 - How could you tell experimentally if TiO2 is an...Ch. 9 - A common prank on college campuses is to switch...Ch. 9 - A plot of In (Pvap) versus 1/T (K) is linear with...Ch. 9 - Prob. 34Q Ch. 9 - Identify the most important types of interparticle...Ch. 9 - Prob. 36E Ch. 9 - Predict which substance in each of the following...Ch. 9 - Consider the compounds CI2, HCI. F2, NaF, and HF....Ch. 9 - Prob. 39E Ch. 9 - Consider the following electrostatic potential...Ch. 9 - In each of the following groups of substances,...Ch. 9 - Prob. 42E Ch. 9 - The shape of the meniscus of water in a glass tube...Ch. 9 - Prob. 44E Ch. 9 - Prob. 45E Ch. 9 - Prob. 46E Ch. 9 - X rays from a copper X-ray tube ( = 154 pm) were...Ch. 9 - The second-order diffraction (n = 2) for a gold...Ch. 9 - A topaz crystal has an interplanar spacing (d) of...Ch. 9 - X rays of wavelength 2.63 were used to analyze a...Ch. 9 - Prob. 51E Ch. 9 - Prob. 52E Ch. 9 - Prob. 53E Ch. 9 - Iridium (Ir) has a face-centered cubic unit cell...Ch. 9 - You are given a small bar of an unknown metal X....Ch. 9 - A metallic solid with atoms in a face-centered...Ch. 9 - Titanium metal has a body-centered cubic unit...Ch. 9 - Barium has a body-centered cubic structure. If the...Ch. 9 - The radius of gold is 144 pm, and the density is...Ch. 9 - The radius of tungsten is 137 pm and the density...Ch. 9 - What fraction of the total volume of a cubic...Ch. 9 - Iron has a density of 7.86 g/cm3 and crystallizes...Ch. 9 - Prob. 63E Ch. 9 - Prob. 64E Ch. 9 - Selenium is a semiconductor used in photocopying...Ch. 9 - Prob. 66E Ch. 9 - Prob. 67E Ch. 9 - Prob. 68E Ch. 9 - The structures of some common crystalline...Ch. 9 - The unit cell for nickel arsenide is shown below....Ch. 9 - Cobalt fluoride crystallizes in a closest packed...Ch. 9 - The compounds Na2O, CdS, and ZrI4. all can be...Ch. 9 - What is the formula for the compound that...Ch. 9 - Prob. 74E Ch. 9 - A certain metal fluoride crystallizes in such a...Ch. 9 - The structure of manganese fluoride can be...Ch. 9 - The unit cell of MgO is shown below l Does MgO...Ch. 9 - In solid KCl the smallest distance between the...Ch. 9 - The CsCl structure is a simple cubic array of...Ch. 9 - MnO has either the NaCI type structure or the CsCI...Ch. 9 - Prob. 81E Ch. 9 - What type of solid will each of the following...Ch. 9 - The memory metal, nitinol, is an alloy of nickel...Ch. 9 - Superalloys have been made of nickel and aluminum....Ch. 9 - Perovskite is a mineral containing calcium,...Ch. 9 - A mineral crystallizes in a cubic closest packed...Ch. 9 - Materials containing the elements Y, Ba, Cu, and O...Ch. 9 - The structures of another class of ceramic,...Ch. 9 - Plot the following data and determine Hvap for...Ch. 9 - From the following data for liquid nitric acid,...Ch. 9 - Prob. 91E Ch. 9 - Prob. 92E Ch. 9 - Prob. 93E Ch. 9 - Diethyl ether (CH3CH2OCH2CH3) was one of the first...Ch. 9 - A substance, X, has the following properties:...Ch. 9 - Use the heating-cooling curve below to answer the...Ch. 9 - The molar heat of fusion of sodium metal is 2.60...Ch. 9 - Prob. 98E Ch. 9 - What quantity of energy does it take to convert...Ch. 9 - Consider a 75.0-g sample of H2O(g) at 125C. What...Ch. 9 - An ice cube tray contains enough water at 22.0C to...Ch. 9 - A 0.250-g chunk of sodium metal is cautiously...Ch. 9 - Prob. 103E Ch. 9 - Prob. 104E Ch. 9 - Prob. 105E Ch. 9 - Prob. 106E Ch. 9 - Prob. 107E Ch. 9 - Consider the following data for xenon: Triple...Ch. 9 - Some of the physical properties of H2O and D2O are...Ch. 9 - Rationalize the following boiling points:Ch. 9 - Prob. 111AE Ch. 9 - Consider the following enthalpy changes:...Ch. 9 - Prob. 113AE Ch. 9 - Boron nitride (BN) exists in two forms. The first...Ch. 9 - Prob. 115AE Ch. 9 - Argon has a cubic closest packed structure as a...Ch. 9 - Prob. 117AE Ch. 9 - A 20.0-g sample of ice at 10.0C is mixed with...Ch. 9 - In regions with dry climates, evaporative coolers...Ch. 9 - The critical point of NH3 is 132C and 111 atm, and...Ch. 9 - Which of the following compound(s) exhibit only...Ch. 9 - Which of the following statements about...Ch. 9 - Prob. 123CWP Ch. 9 - Aluminum has an atomic radius of 143 pm and forms...Ch. 9 - Pyrolusite is a mineral containing manganese ions...Ch. 9 - The structure of the compound K2O is best...Ch. 9 - Prob. 127CWP Ch. 9 - Some ice cubes at 0c with a total mass of 403 g...Ch. 9 - The enthalpy of vaporization for acetone is 32.0...Ch. 9 - Prob. 130CWP Ch. 9 - When I mole of benzene is vaporized at a constant...Ch. 9 - Prob. 132CP Ch. 9 - Using the heats of fusion and vaporization for...Ch. 9 - Prob. 134CP Ch. 9 - Consider two different organic compounds, each...Ch. 9 - Prob. 136CP Ch. 9 - Prob. 137CP Ch. 9 - Prob. 138CP Ch. 9 - Prob. 139CP Ch. 9 - Prob. 140CP Ch. 9 - Mn crystallizes in the same type of cubic unit...Ch. 9 - Prob. 142CP Ch. 9 - Some water is placed in a sealed glass container...Ch. 9 - The molar enthalpy of vaporization of water at 373...Ch. 9 - Prob. 145CP Ch. 9 - Rubidium chloride has the sodium chloride...Ch. 9 - Prob. 147IP Ch. 9 - A metal burns in air at 600c under high pressure...Ch. 9 - Prob. 149IP Ch. 9 - General Zod has sold Lex Luthor what Zod claims to...

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X rays from a copper X-ray tube ( λ = 154 pm) were diffracted at an angle of 14.22 degrees by a crystal of silicon. Assuming first-order diffraction (n = 1 in the Bragg equation), what is the interplanar spacing in silicon?

Solution Summary: The author explains how the structure of a crystalline solid can be determined by X-ray diftion method using the Bragg equation.

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Chapter 9 Solutions