EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 9780100552234
Author: ZUMDAHL
Publisher: YUZU
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Chapter 9, Problem 32Q
A common prank on college campuses is to switch the salt and sugar on dining hall tables, which is usually easy because the substances look so much alike. Yet, despite the similarity in their appearance, these two substances differ greatly in their properties, since one is a molecular solid and the other is an ionic solid. How do the properties differ and why?
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Chapter 9 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 9 - What are intermolecular forces? How do they differ...Ch. 9 - Define the following terms and describe how each...Ch. 9 - Compare and contrast solids, liquids, and gases.Ch. 9 - Prob. 4RQCh. 9 - What is a lattice? What is a unit cell? Describe a...Ch. 9 - What is closest packing? What is the difference...Ch. 9 - Describe, in general, the structures of ionic...Ch. 9 - Prob. 9RQCh. 9 - Prob. 10RQCh. 9 - Compare and contrast the phase diagrams of water...
Ch. 9 - It is possible to balance a paper clip on the...Ch. 9 - Prob. 2ALQCh. 9 - Prob. 3ALQCh. 9 - Prob. 4ALQCh. 9 - Prob. 5ALQCh. 9 - Prob. 6ALQCh. 9 - Prob. 7ALQCh. 9 - Prob. 8ALQCh. 9 - Prob. 9ALQCh. 9 - Prob. 10ALQCh. 9 - Prob. 11ALQCh. 9 - Prob. 12QCh. 9 - In the diagram below, which lines represent the...Ch. 9 - Prob. 14QCh. 9 - Atoms are assumed to touch in closest packed...Ch. 9 - Define critical temperature and critical pressure....Ch. 9 - Prob. 17QCh. 9 - Prob. 18QCh. 9 - Prob. 19QCh. 9 - Prob. 20QCh. 9 - Prob. 21QCh. 9 - A common response to hearing that the temperature...Ch. 9 - Prob. 23QCh. 9 - Prob. 24QCh. 9 - When wet laundry is hung on a clothesline on a...Ch. 9 - Cake mixes and other packaged foods that require...Ch. 9 - You have three covalent compounds with three very...Ch. 9 - Prob. 28QCh. 9 - Compare and contrast the structures of the...Ch. 9 - Prob. 30QCh. 9 - How could you tell experimentally if TiO2 is an...Ch. 9 - A common prank on college campuses is to switch...Ch. 9 - A plot of In (Pvap) versus 1/T (K) is linear with...Ch. 9 - Prob. 34QCh. 9 - Identify the most important types of interparticle...Ch. 9 - Prob. 36ECh. 9 - Predict which substance in each of the following...Ch. 9 - Consider the compounds CI2, HCI. F2, NaF, and HF....Ch. 9 - Prob. 39ECh. 9 - Consider the following electrostatic potential...Ch. 9 - In each of the following groups of substances,...Ch. 9 - Prob. 42ECh. 9 - The shape of the meniscus of water in a glass tube...Ch. 9 - Prob. 44ECh. 9 - Prob. 45ECh. 9 - Prob. 46ECh. 9 - X rays from a copper X-ray tube ( = 154 pm) were...Ch. 9 - The second-order diffraction (n = 2) for a gold...Ch. 9 - A topaz crystal has an interplanar spacing (d) of...Ch. 9 - X rays of wavelength 2.63 were used to analyze a...Ch. 9 - Prob. 51ECh. 9 - Prob. 52ECh. 9 - Prob. 53ECh. 9 - Iridium (Ir) has a face-centered cubic unit cell...Ch. 9 - You are given a small bar of an unknown metal X....Ch. 9 - A metallic solid with atoms in a face-centered...Ch. 9 - Titanium metal has a body-centered cubic unit...Ch. 9 - Barium has a body-centered cubic structure. If the...Ch. 9 - The radius of gold is 144 pm, and the density is...Ch. 9 - The radius of tungsten is 137 pm and the density...Ch. 9 - What fraction of the total volume of a cubic...Ch. 9 - Iron has a density of 7.86 g/cm3 and crystallizes...Ch. 9 - Prob. 63ECh. 9 - Prob. 64ECh. 9 - Selenium is a semiconductor used in photocopying...Ch. 9 - Prob. 66ECh. 9 - Prob. 67ECh. 9 - Prob. 68ECh. 9 - The structures of some common crystalline...Ch. 9 - The unit cell for nickel arsenide is shown below....Ch. 9 - Cobalt fluoride crystallizes in a closest packed...Ch. 9 - The compounds Na2O, CdS, and ZrI4. all can be...Ch. 9 - What is the formula for the compound that...Ch. 9 - Prob. 74ECh. 9 - A certain metal fluoride crystallizes in such a...Ch. 9 - The structure of manganese fluoride can be...Ch. 9 - The unit cell of MgO is shown below l Does MgO...Ch. 9 - In solid KCl the smallest distance between the...Ch. 9 - The CsCl structure is a simple cubic array of...Ch. 9 - MnO has either the NaCI type structure or the CsCI...Ch. 9 - Prob. 81ECh. 9 - What type of solid will each of the following...Ch. 9 - The memory metal, nitinol, is an alloy of nickel...Ch. 9 - Superalloys have been made of nickel and aluminum....Ch. 9 - Perovskite is a mineral containing calcium,...Ch. 9 - A mineral crystallizes in a cubic closest packed...Ch. 9 - Materials containing the elements Y, Ba, Cu, and O...Ch. 9 - The structures of another class of ceramic,...Ch. 9 - Plot the following data and determine Hvap for...Ch. 9 - From the following data for liquid nitric acid,...Ch. 9 - Prob. 91ECh. 9 - Prob. 92ECh. 9 - Prob. 93ECh. 9 - Diethyl ether (CH3CH2OCH2CH3) was one of the first...Ch. 9 - A substance, X, has the following properties:...Ch. 9 - Use the heating-cooling curve below to answer the...Ch. 9 - The molar heat of fusion of sodium metal is 2.60...Ch. 9 - Prob. 98ECh. 9 - What quantity of energy does it take to convert...Ch. 9 - Consider a 75.0-g sample of H2O(g) at 125C. What...Ch. 9 - An ice cube tray contains enough water at 22.0C to...Ch. 9 - A 0.250-g chunk of sodium metal is cautiously...Ch. 9 - Prob. 103ECh. 9 - Prob. 104ECh. 9 - Prob. 105ECh. 9 - Prob. 106ECh. 9 - Prob. 107ECh. 9 - Consider the following data for xenon: Triple...Ch. 9 - Some of the physical properties of H2O and D2O are...Ch. 9 - Rationalize the following boiling points:Ch. 9 - Prob. 111AECh. 9 - Consider the following enthalpy changes:...Ch. 9 - Prob. 113AECh. 9 - Boron nitride (BN) exists in two forms. The first...Ch. 9 - Prob. 115AECh. 9 - Argon has a cubic closest packed structure as a...Ch. 9 - Prob. 117AECh. 9 - A 20.0-g sample of ice at 10.0C is mixed with...Ch. 9 - In regions with dry climates, evaporative coolers...Ch. 9 - The critical point of NH3 is 132C and 111 atm, and...Ch. 9 - Which of the following compound(s) exhibit only...Ch. 9 - Which of the following statements about...Ch. 9 - Prob. 123CWPCh. 9 - Aluminum has an atomic radius of 143 pm and forms...Ch. 9 - Pyrolusite is a mineral containing manganese ions...Ch. 9 - The structure of the compound K2O is best...Ch. 9 - Prob. 127CWPCh. 9 - Some ice cubes at 0c with a total mass of 403 g...Ch. 9 - The enthalpy of vaporization for acetone is 32.0...Ch. 9 - Prob. 130CWPCh. 9 - When I mole of benzene is vaporized at a constant...Ch. 9 - Prob. 132CPCh. 9 - Using the heats of fusion and vaporization for...Ch. 9 - Prob. 134CPCh. 9 - Consider two different organic compounds, each...Ch. 9 - Prob. 136CPCh. 9 - Prob. 137CPCh. 9 - Prob. 138CPCh. 9 - Prob. 139CPCh. 9 - Prob. 140CPCh. 9 - Mn crystallizes in the same type of cubic unit...Ch. 9 - Prob. 142CPCh. 9 - Some water is placed in a sealed glass container...Ch. 9 - The molar enthalpy of vaporization of water at 373...Ch. 9 - Prob. 145CPCh. 9 - Rubidium chloride has the sodium chloride...Ch. 9 - Prob. 147IPCh. 9 - A metal burns in air at 600c under high pressure...Ch. 9 - Prob. 149IPCh. 9 - General Zod has sold Lex Luthor what Zod claims to...
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- A common prank on college campuses is to switch the salt and sugar on dining hall tables. which is usually easy because the substances look so much alike. Yet, despite the similarity in their appearance, these two substances differ greatly in their properties because one is a molecular solid and the other is an ionic solid. How do the properties differ and why?arrow_forwardAn amorphous solid can sometimes be converted to a crystalline solid by a process called annealing. Annealing consists of heating the substance to a temperature just below the melting point of the crystalline form and then cooling it slowly. Explain why this process helps produce a crystalline solid.arrow_forwardWhat types of forces exist between the individual particles in an ionic solid? Are these threes relatively strong or relatively weak?arrow_forward
- Potassium bromide has the same lattice structure as NaCl. Given the ionic radii of K+ (133 pm) and Br (196 pm), calculate the density of KBr.arrow_forwardAre changes in state physical or chemical changes? Explain. What type of forces must be overcome to melt or vaporize a substance (are these forces intramolecular or intermolecular)? Define the molar heat of fusion and molar heat of vaporization. Why is the molar heat of vaporization of water so much larger than its molar heat of fusion? Why does the boiling point of a liquid vary with altitude?arrow_forwardConsider the iodine monochloride molecule, ICI. Because chlorine is more electronegative than iodine, this molecule is a dipole. How would you expect iodine monochloride molecules in the gaseous state to orient themselves with respect to each other as the sample is cooled and the molecules begin to aggregate? Sketch the orientation you would expect.arrow_forward
- Consider two different organic compounds, each with the formula C2H6O. One of these compounds is a liquid at room conditions and the other is a gas. Write Lewis structures consistent with this observation, and explain your answer. (Hint: The oxygen atom in both structures satisfies the octet rule with two bonds and two lone pairs.)arrow_forwardSilicon carbide, SiC, is a very hard, high-melting solid. What kind of crystal forces account for these properties?arrow_forwardExplain why the enthalpies of vaporization of the following substances increase in the order CH4NH3H2O, even though all three substances have approximately the same molar mass.arrow_forward
- 8.103 In previous chapters, we have noted that cryolite is used in refining aluminum. Use the web to look up what this addition does for the process, and relate it to the concepts of intermolecular forces from this chapter.arrow_forwardThe CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69). Given that the density of cesium chloride is 3.97 g/cm3, and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent Cs+ and Cl ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of Cs+ is 169 pm, and the ionic radius of Cl is 181 pm.arrow_forwardA 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0C. The reaction is 2Na(s)+2H2O(l)2NaOH(aq)+H2(g)H=368kJ Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/gc, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.arrow_forward
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