Whetherthe normal melting point of substance X would be less than or greater than or equal to 225°C to be explained. Concept introduction Freezing point: Freezing point is defined as the temperature at which liquid into solid. Boiling point: Boiling point is temperature at which the liquid into gas. Elevation of boiling point: Elevation of boiling point of a liquid is occurrence that boiling point of a liquid would be greater when another substance is added to it. Resulting, the boiling point becomes higher than the pure solvent. Depression of freezing point: Depression of freezing point is reducing in freezing point of a solvent when added non volatile solute. Volatile substance means easily vaporized at room temperature and non volatile means does not easily evaporate at room temperature.
Whetherthe normal melting point of substance X would be less than or greater than or equal to 225°C to be explained. Concept introduction Freezing point: Freezing point is defined as the temperature at which liquid into solid. Boiling point: Boiling point is temperature at which the liquid into gas. Elevation of boiling point: Elevation of boiling point of a liquid is occurrence that boiling point of a liquid would be greater when another substance is added to it. Resulting, the boiling point becomes higher than the pure solvent. Depression of freezing point: Depression of freezing point is reducing in freezing point of a solvent when added non volatile solute. Volatile substance means easily vaporized at room temperature and non volatile means does not easily evaporate at room temperature.
Solution Summary: The author explains that the normal melting point of substance X should be greater than 225°C.
Interpretation: Whetherthe normal melting point of substance X would be less than or greater than or equal to
225°C to be explained.
Concept introduction
Freezing point: Freezing point is defined as the temperature at which liquid into solid.
Boiling point: Boiling point is temperature at which the liquid into gas.
Elevation of boiling point: Elevation of boiling point of a liquid is occurrence that boiling point of a liquid would be greater when another substance is added to it. Resulting, the boiling point becomes higher than the pure solvent.
Depression of freezing point: Depression of freezing point is reducing in freezing point of a solvent when added non volatile solute. Volatile substance means easily vaporized at room temperature and non volatile means does not easily evaporate at room temperature.
21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to
most acidic).
OH
OH
SH
NH2
8
NH3
OH
(b)
OH
OH
OH
(c)
& & &
CH3
NO2
21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol.
OH
OH
OH
OH
PK 10.0
PK 8.81
PK 9.28
PK 9.81
identify which spectrum is for acetaminophen and which is for phenacetin
The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?
Chapter 9 Solutions
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