A 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0°C. The reaction is 2 Na ( s ) + 2 H 2 O ( l ) → 2 NaOH ( a q ) + H 2 ( g ) Δ H = − 368 kJ Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/g∙°c, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.
A 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0°C. The reaction is 2 Na ( s ) + 2 H 2 O ( l ) → 2 NaOH ( a q ) + H 2 ( g ) Δ H = − 368 kJ Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/g∙°c, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.
Solution Summary: The author explains that the final temperature of an ice has to be calculated.
A 0.250-g chunk of sodium metal is cautiously dropped into a mixture of 50.0 g water and 50.0 g ice, both at 0°C. The reaction is
2
Na
(
s
)
+
2
H
2
O
(
l
)
→
2
NaOH
(
a
q
)
+
H
2
(
g
)
Δ
H
=
−
368
kJ
Assuming no heat loss to the surroundings, will the ice melt? Assuming the final mixture has a specific heat capacity of 4.18 J/g∙°c, calculate the final temperature. The enthalpy of fusion for ice is 6.02 kJ/mol.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 9 Solutions
Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell