
Concept explainers
Interpretation:
The reason for chalk having higher melting point than motor oil and water has to be justified.
Concept introduction:
- Matter exists in three distinct physical forms – solid, liquid and gas. There are two types of interactions present in matter – intramolecular meaning, “within the molecule” and intermolecular meaning “between the molecules”.
- Intramolecular force refers to the type of bonding that holds the atoms or ions together to form a stable molecule. Intermolecular force refers to the type of interaction that exists between the so formed molecules by bonding.
- The physical properties of a substance such as boiling point, melting point, vapor pressure, etc., of a substance depend on the type and strength of the intermolecular force exists in it. Higher the strength of these forces, higher will be the melting and boiling point. The classification is summarized as follows –
Figure 1
Intramolecular forces are nothing but the type of bonding between them. Ionic compounds have electrostatic force of attraction, called “ionic bond” the strongest one. Atoms having high electronegativity difference with each other forms ionic bond. An atom having slight electronegativity difference with other atom forms covalent bonds. They are of two types, that is polar and non-polar depend upon the polarity of the atoms. Metallic bond is formed between the metal atoms.
Figure 2
Intermolecular forces are Van der Waals forces. They are weak and are of categories - London dispersion forces, dipole-dipole forces and hydrogen bonding. Hydrogen bonding is relatively the strongest one. It is formed in polar covalent compounds containing hydrogen and other high electronegativity like fluorine, oxygen or nitrogen. These atoms in a molecule partially bond to hydrogen of the other same molecule or within a molecule.

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Chapter 9 Solutions
Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
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- Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and the follow the arrows to draw the intermediate and product in this reaction or mechanistic step(s).arrow_forwardCurved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the curved arrows to draw the intermediates and product of the following reaction or mechanistic step(s).arrow_forwardCurved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow the arrows to draw the intermediate and the product in this reaction or mechanistic step(s).arrow_forward
- Look at the following pairs of structures carefully to identify them as representing a) completely different compounds, b) compounds that are structural isomers of each other, c) compounds that are geometric isomers of each other, d) conformers of the same compound (part of structure rotated around a single bond) or e) the same structure.arrow_forwardGiven 10.0 g of NaOH, what volume of a 0.100 M solution of H2SO4 would be required to exactly react all the NaOH?arrow_forward3.50 g of Li are combined with 3.50 g of N2. What is the maximum mass of Li3N that can be produced? 6 Li + N2 ---> 2 Li3Narrow_forward
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