CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
4th Edition
ISBN: 9781260562620
Author: SMITH
Publisher: MCG
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Chapter 8.7, Problem 8.14PP
What is the concentration of a solution formed by diluting 25.0 mL of a 3.8 M glucosesolution to 275 mL?
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 8 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
Ch. 8.1 - Classify each substance as a heterogeneous...Ch. 8.1 - Use the appearance of each product to classify it...Ch. 8.2 - Consider the following diagrams for an aqueous...Ch. 8.2 - Classify each solution as an electrolyte or...Ch. 8.2 - Using the given number of moles, determine how...Ch. 8.2 - Prob. 8.2PPCh. 8.2 - A solution contains the following ions:...Ch. 8.2 - If a solution contains 125 mEq of Na+ per liter,...Ch. 8.3 - Which compounds are water soluble? a. NaNO3 b. CH4...Ch. 8.3 - Prob. 8.7P
Ch. 8.3 - Use the solubility rules to predict whether the...Ch. 8.3 - Use the solubility rules for ionic compounds to...Ch. 8.4 - Why does a soft drink become "flat" faster when it...Ch. 8.4 - Predict the effect each change has on the...Ch. 8.5 - A commercial mouthwash contains 4.3 g of ethanol...Ch. 8.5 - What is the weight/volume percent concentration of...Ch. 8.5 - Prob. 8.6PPCh. 8.5 - Prob. 8.7PPCh. 8.5 - A drink sold in a health food store contains 0.50%...Ch. 8.5 - Prob. 8.12PCh. 8.5 - What is the concentration in parts per million of...Ch. 8.6 - Prob. 8.10PPCh. 8.6 - Prob. 8.13PCh. 8.6 - Prob. 8.11PPCh. 8.6 - Prob. 8.12PPCh. 8.6 - How many grams of NaCl are contained in each of...Ch. 8.6 - How many milliliters of a 0.25 M sucrose solution...Ch. 8.7 - What is the concentration of a solution formed by...Ch. 8.7 - If the solution of A+B- in X is diluted, which...Ch. 8.7 - Prob. 8.15PPCh. 8.7 - Prob. 8.16PCh. 8.8 - What is the boiling point of a solution prepared...Ch. 8.8 - Representations A, B, and C each show an aqueous...Ch. 8.8 - Prob. 8.18PPCh. 8.8 - What is the melting point of a solution that is...Ch. 8.9 - Which solution in each pair exerts the greater...Ch. 8.9 - Prob. 8.19PCh. 8.9 - Consider the two aqueous solutions separated by a...Ch. 8.9 - What happens to a red blood cell when it is placed...Ch. 8 - Prob. 21PCh. 8 - Prob. 22PCh. 8 - Prob. 23PCh. 8 - Which representation of molecular art better shows...Ch. 8 - Classify each of the following as a solution,...Ch. 8 - Classify each of the following as a solution,...Ch. 8 - Prob. 27PCh. 8 - Label each diagram as a strong electrolyte, weak...Ch. 8 - Prob. 29PCh. 8 - Prob. 30PCh. 8 - Prob. 31PCh. 8 - Prob. 32PCh. 8 - Consider a mixture of two substances shown in blue...Ch. 8 - Which diagram (C or D) best represents what occurs...Ch. 8 - If the solubilityofKClin 100 mL of H2O is 34 g at...Ch. 8 - If the solubilityofsucrosein 100 mL of H2O is 204...Ch. 8 - Prob. 37PCh. 8 - Prob. 38PCh. 8 - Using the ball-and-stick model for methanol...Ch. 8 - Prob. 40PCh. 8 - Prob. 41PCh. 8 - Prob. 42PCh. 8 - Prob. 43PCh. 8 - Prob. 44PCh. 8 - Prob. 45PCh. 8 - Prob. 46PCh. 8 - Prob. 47PCh. 8 - How is the solubility of helium gas in water...Ch. 8 - Use the solubility rules listed in Section 8.3B to...Ch. 8 - Use the solubility rules listed in Section 8.3B to...Ch. 8 - Prob. 51PCh. 8 - Prob. 52PCh. 8 - Prob. 53PCh. 8 - Prob. 54PCh. 8 - Prob. 55PCh. 8 - Prob. 56PCh. 8 - Prob. 57PCh. 8 - Prob. 58PCh. 8 - How would you use a 250-mL volumetric flask to...Ch. 8 - How would you use a 250-mLvolumetric flask to...Ch. 8 - Prob. 61PCh. 8 - Prob. 62PCh. 8 - Prob. 63PCh. 8 - Prob. 64PCh. 8 - Prob. 65PCh. 8 - What is the molarity of a 20.0% (v/v) aqueous...Ch. 8 - Prob. 67PCh. 8 - Prob. 68PCh. 8 - Prob. 69PCh. 8 - Prob. 70PCh. 8 - Prob. 71PCh. 8 - Prob. 72PCh. 8 - Prob. 73PCh. 8 - Prob. 74PCh. 8 - Prob. 75PCh. 8 - Prob. 76PCh. 8 - Prob. 77PCh. 8 - Representations A (containing 1.0 mol ofNaCl) and...Ch. 8 - What is the boiling point of a solution that...Ch. 8 - Prob. 80PCh. 8 - If 150 g of ethylene glycol (C2H6O2) is added to...Ch. 8 - Prob. 82PCh. 8 - Prob. 83PCh. 8 - Prob. 84PCh. 8 - Which solution in each pair has the higher melting...Ch. 8 - Prob. 86PCh. 8 - A flask contains two compartments (A and B) with...Ch. 8 - A flask contains two compartments (A and B) with...Ch. 8 - The molecular art illustrates a red blood cell in...Ch. 8 - Prob. 90PCh. 8 - Prob. 91PCh. 8 - Explain why more sugar dissolves in a cup of hot...Ch. 8 - If the concentration of glucose in the blood is...Ch. 8 - Prob. 94PCh. 8 - Mannitol, a carbohydrate, is supplied as a 25%...Ch. 8 - A patient receives 750 ml, of a 10.% (w/v) aqueous...Ch. 8 - Explain why a cucumber placed in a concentrated...Ch. 8 - Explain why a cucumber placed in a concentrated...Ch. 8 - Prob. 99PCh. 8 - Prob. 100PCh. 8 - Prob. 101PCh. 8 - Prob. 102PCh. 8 - The therapeutic concentration—the concentration...Ch. 8 - Prob. 104CP
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY