Answered: 8b. Explain, using key intermediates,…

8b. Explain, using key intermediates, why the above two products are formed instead of the 1,2-and 1,4- products shown in the reaction below. CI

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter25: Enolate & Enol Nucleophiles

Section: Chapter Questions

Problem 7E

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Question

The question below asks why the products shown are NOT the correct products. I asked this already, and the person explained why those are the correct products, as opposed to what we would think should be the correct products. That's the opposite of what the question was asking. Why are they not the correct products? A reaction mechanism for how we arrive at the correct products is requested ("using key intermediates"). In other words, why is HCl added to the terminal alkene rather than the internal alkene?

8b. Explain, using key intermediates, why the above two products are formed instead of the 1,2-and 1,4- products
shown in the reaction below.
CI

Definition Definition Organic compounds that contain at least one double bond between carbon-carbon atoms. The general molecular formula for alkenes with one double bond is C n H 2n .

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