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2. Show the complete mechanisms for the following substitution react reaction arrows for each step. HBr NaSH DMSO H₂O

2. Show the complete mechanisms for the following substitution react reaction arrows for each step. HBr NaSH DMSO H₂O

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Title: Understanding Substitution Reaction Mechanisms** --- **Exercise 2: Substitution Reaction Mechanisms** In this exercise, you are required to demonstrate the complete mechanisms for the following substitution reactions and provide the reaction arrows for each step. **Reactions:** 1. **Cyclohexanol Reaction:** - **Reactant:** Cyclohexanol - **Reagent:** HBr - **Structure:** Six-membered carbon ring (cyclohexane) with an -OH group attached. 2. **Benzyl Chloride Reaction:** - **Reactant:** Benzyl chloride - **Reagent:** NaSH - **Solvent:** DMSO (Dimethyl sulfoxide) - **Structure:** Benzene ring attached to a -CH2Cl group. 3. **Tertiary Butyl Halide Reaction:** - **Reactant:** Tertiary butyl halide - **Reagent:** H2O - **Structure:** Three methyl groups attached to a central carbon, which is also bonded to a halogen. **Instructions:** - Use curved arrows to indicate the movement of electron pairs during the reactions. - Identify the leaving group in each reaction. - Clearly show the formation of any intermediates or transition states. --- This section is tailored to help students visualize and understand the substitution reaction mechanisms, emphasizing step-by-step electron movement essential for mastering organic chemistry concepts.
Transcribed Image Text:**Title: Understanding Substitution Reaction Mechanisms** --- **Exercise 2: Substitution Reaction Mechanisms** In this exercise, you are required to demonstrate the complete mechanisms for the following substitution reactions and provide the reaction arrows for each step. **Reactions:** 1. **Cyclohexanol Reaction:** - **Reactant:** Cyclohexanol - **Reagent:** HBr - **Structure:** Six-membered carbon ring (cyclohexane) with an -OH group attached. 2. **Benzyl Chloride Reaction:** - **Reactant:** Benzyl chloride - **Reagent:** NaSH - **Solvent:** DMSO (Dimethyl sulfoxide) - **Structure:** Benzene ring attached to a -CH2Cl group. 3. **Tertiary Butyl Halide Reaction:** - **Reactant:** Tertiary butyl halide - **Reagent:** H2O - **Structure:** Three methyl groups attached to a central carbon, which is also bonded to a halogen. **Instructions:** - Use curved arrows to indicate the movement of electron pairs during the reactions. - Identify the leaving group in each reaction. - Clearly show the formation of any intermediates or transition states. --- This section is tailored to help students visualize and understand the substitution reaction mechanisms, emphasizing step-by-step electron movement essential for mastering organic chemistry concepts.
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