a) Interpretation: The product expected from oxymercuration-demercuration of 1-pentene is to be given. Concept introduction: In the oxymercuration-demercuration process, in the first step, the electrophilic addition of Hg 2+ to the double bond in alkene takes place to give a mercurinium ion. In the next step the mercurinium ion reacts with water to yield an organomercury product. In the last step, NaBH 4 removes mercury from the organomercury product to give a more highly substituted alcohol, corresponding to Markovnikov regiochemistry, as the product. To give: The product expected from oxymercuration-demercuration of 1-pentene.

Question

1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]

Answer 1

Question

Chapter 8.4, Problem 7P

Interpretation Introduction

a)

Interpretation:

The product expected from oxymercuration-demercuration of 1-pentene is to be given.

Concept introduction:

In the oxymercuration-demercuration process, in the first step, the electrophilic addition of Hg²⁺ to the double bond in alkene takes place to give a mercurinium ion. In the next step the mercurinium ion reacts with water to yield an organomercury product. In the last step, NaBH₄ removes mercury from the organomercury product to give a more highly substituted alcohol, corresponding to Markovnikov regiochemistry, as the product.

To give:

The product expected from oxymercuration-demercuration of 1-pentene.

Interpretation Introduction

b)

Interpretation:

The product expected from oxymercuration-demercuration of 2-methyl-2-pentene is to be given.

Concept introduction:

In the oxymercuration-demercuration process, in the first step, the electrophilic addition of Hg²⁺ to the alkene takes place to give a mercurinium ion. In the next step, the mercurinium ion reacts with water to yield an organomercury product. In the last step, reaction with NaBH₄ removes mercury from the organomercury product to give a more highly substituted alcohol, corresponding to Markovnikov regiochemistry, as the product.

To give:

The product expected from oxymercuration-demercuration of 2-methyl-2-pentene.

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