The electrostatic potential maps of the given compounds has to be explained. Concept Introduction: Criteria for Aromaticity : A molecule must be cyclic. Every atom in the ring must have a p-orbital. The molecule must be planar. π- Cloud must contain an odd number of pairs of π-electrons . Heterocyclic compounds: A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds. Electrostatic potential map: Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

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Answer 1

Question

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

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Draw the structure of ,-diethyl--propylthiopentane. With explanation

A. Provide a stepwise mechanism for the formation of nerolidyl pyrophosphate fromfarnesylpyrophosphate B. Provide a stepwise mechanism for the formation of carbocation 1 from nerolidylpyrophosphate. Number the backbone carbons of nerolidyl pyrophosphate from 1 to 11 as shown, andinclude the carbon numbering in your structure of 1 C. Following from B, give an arrow-pushing mechanism to convert 1 to 2 and 2 to 3. Use thebackbone carbon numbering from 1 to indicate where carbon atoms ended up in 2 and 3 D. In addition to forming epi-cedrol, carbocation 3 gives three minor byproducts: a diastereomericalcohol and two alkenes. Draw mechanisms that could give rise to these three products

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Answer 2

Question

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

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Answer 3

Question

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Expert Solution & Answer

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Answer 4

Question

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Expert Solution & Answer

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Answer 5

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 6

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 7

Chapter 8.20, Problem 60P

a)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 8

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 9

b)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compound has to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 10

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 11

c)

Interpretation Introduction

Interpretation: The electrostatic potential maps of the given compounds to be explained.

Concept Introduction:

Criteria for Aromaticity:

A molecule must be cyclic.

Every atom in the ring must have a p-orbital.

The molecule must be planar.

π- Cloud must contain an odd number of pairs of π-electrons.

Heterocyclic compounds:

A cyclic compound in which one or more of the ring atoms is an atom other than carbon is known as heterocyclic compounds.

Electrostatic potential map:

Electrostatic potential maps that are very useful three dimensional diagrams of molecule. They enable us to visualize the charge distributions of molecules and charge related properties of molecules and also to visualize the size and shape of molecules.

Answer 12

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Answer 15

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

Solution Summary: The author explains that the electrostatic potential maps of the given compounds have to be explained.

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