The type of stereoisomers formed by the given reaction has to be predicted. Concept Introduction: Effect of delocalized electrons on the product of the reaction: The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product. Rule: The stabilities of carbocation are, Benzyl cation = allyl cation = 3 ∘ carbocation > 2 ∘ carbocation > 1 ∘ carbocation > methyl cation > vinyl cation

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Answer 1

Question

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

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Answer 2

Question

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Expert Solution & Answer

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See solution

Answer 3

Question

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Expert Solution & Answer

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Answer 4

Question

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Expert Solution & Answer

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Answer 5

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 6

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 7

Chapter 8.12, Problem 30P

(a)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 8

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 9

b)

Interpretation Introduction

Interpretation:

The type of stereoisomers formed by the given reaction has to be predicted.

Concept Introduction:

Effect of delocalized electrons on the product of the reaction:

The presence of delocalizes electrons while electrophilic addition or substitution the cation intermediate formed is shifted to stable carbocation form at higher rate, and that leads to the product.

Rule: The stabilities of carbocation are,

Benzyl cation = allyl cation = 3∘carbocation > 2∘ carbocation > 1∘ carbocation > methyl cation > vinyl cation

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

Solution Summary: The author explains that the type of stereoisomers formed by the given reaction has to be predicted.

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