The value of ‘n’ has to be estimated. Concept Introduction: Criteria for Aromaticity: 1. A molecule must be cyclic. 2. Every atom in the ring must have a p-orbital. 3. The molecule must be planar. 4. π- Cloud must contain an odd number of pairs of π-electrons .

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Answer 1

Question

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Answer 2

Question

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

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Answer 3

Question

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

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Answer 4

Question

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

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Answer 5

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Answer 6

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Answer 7

Chapter 8.17, Problem 49P

(a)

Interpretation Introduction

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Answer 8

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Answer 9

(b)

Interpretation Introduction

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

The value of ‘n’ has to be estimated. Concept Introduction: Criteria for Aromaticity: 1. A molecule must be cyclic. 2. Every atom in the ring must have a p-orbital. 3. The molecule must be planar. 4. π- Cloud must contain an odd number of pairs of π-electrons .

Solution Summary: The author explains that 'n' stands for a whole number, if the number of pi-electrons satisfies the Huckel’s rule (4n+2)

Concept explainers

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

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Chapter 8 Solutions

The value of ‘n’ has to be estimated. Concept Introduction: Criteria for Aromaticity: 1. A molecule must be cyclic. 2. Every atom in the ring must have a p-orbital. 3. The molecule must be planar. 4. π- Cloud must contain an odd number of pairs of π-electrons .

Solution Summary: The author explains that 'n' stands for a whole number, if the number of pi-electrons satisfies the Huckel’s rule (4n+2)

Concept explainers

Interpretation: The value of ‘n’ has to be estimated. Concept Introduction: Criteria for Aromaticity: 1. A molecule must be cyclic. 2. Every atom in the ring must have a p-orbital. 3. The molecule must be planar. 4. π- Cloud must contain an odd number of pairs of π-electrons.

Interpretation: The prediction of aromaticity has to be estimated. Concept Introduction: Criteria for Aromaticity: 1. A molecule must be cyclic. 2. Every atom in the ring must have a p-orbital. 3. The molecule must be planar. 4. π- Cloud must contain an odd number of pairs of π-electrons.

Want to see the full answer?

Chapter 8 Solutions

Interpretation: The value of ‘n’ has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.

Interpretation: The prediction of aromaticity has to be estimated.

Concept Introduction:

Criteria for Aromaticity:

1. A molecule must be cyclic.

2. Every atom in the ring must have a p-orbital.

3. The molecule must be planar.

4. π- Cloud must contain an odd number of pairs of π-electrons.