General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Textbook Question
Chapter 8.1, Problem 8.1E
Look at the following orbital diagrams and electron configurations. Which are possible and which are not, according to the Pauli exclusion principle? Explain.
- a
- b
- c
- d 1s22s22p4
- e 1s22s42p2
- f 1s22s22p63s23p103d10
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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that
both of them
have a molecular ion peak at m/2 =128. However ketone
(A) has a fragment peak at m/2 = 99 and 72
while ketone (B) snowed a
fragment peak at m/2 = 113 and 58.
9) Propose the most plausible structures for both ketones
b) Explain how you arrived at your conclusion by drawing the
Structures of the distinguishing fragments for each ketone,
including their fragmentation mechanisms.
Part V. Draw the structure of compound tecla using the IR spectrum Cobtained from
the compound in KBr pellet) and the mass spectrum as shown below.
The mass spectrum of compound Tesla showed strong mt peak at 71.
TRANSMITTANCE
LOD
Relative Intensity
100
MS-NW-1539
40
20
80
T
44
55
10
15
20
25
30
35
40
45
50
55
60
65
70
75
m/z
D
4000
3000
2000
1500
1000
500
HAVENUMBERI-11
Chapter 8 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 8.1 - Look at the following orbital diagrams and...Ch. 8.2 - Imagine a world in which the Pauli principle is No...Ch. 8.3 - Use the building-up principle to obtain the...Ch. 8.3 - Prob. 8.3ECh. 8.3 - Prob. 8.4ECh. 8.3 - Prob. 8.2CCCh. 8.4 - Write an orbital diagram for the ground state of...Ch. 8.6 - Prob. 8.6ECh. 8.6 - The first ionization energy of the chlorine atom...Ch. 8.6 - Prob. 8.8E
Ch. 8.6 - Prob. 8.3CCCh. 8.7 - Prob. 8.4CCCh. 8 - Describe the experiment of Stern and Gerlach. How...Ch. 8 - Prob. 8.2QPCh. 8 - Prob. 8.3QPCh. 8 - What is the maximum number of electrons that can...Ch. 8 - List the orbitals in order of increasing orbital...Ch. 8 - Prob. 8.6QPCh. 8 - Prob. 8.7QPCh. 8 - Prob. 8.8QPCh. 8 - Prob. 8.9QPCh. 8 - Prob. 8.10QPCh. 8 - Describe the major trends that emerge when atomic...Ch. 8 - Prob. 8.12QPCh. 8 - What main group in the periodic table has elements...Ch. 8 - Prob. 8.14QPCh. 8 - Prob. 8.15QPCh. 8 - Prob. 8.16QPCh. 8 - What is the name of the alkali metal atom with...Ch. 8 - What would you predict for the atomic number of...Ch. 8 - Prob. 8.19QPCh. 8 - Prob. 8.20QPCh. 8 - Prob. 8.21QPCh. 8 - Prob. 8.22QPCh. 8 - Prob. 8.23QPCh. 8 - Prob. 8.24QPCh. 8 - Prob. 8.25QPCh. 8 - Which of the following atoms, designated by their...Ch. 8 - Prob. 8.27QPCh. 8 - Prob. 8.28QPCh. 8 - Periodic Properties I A hypothetical element, X,...Ch. 8 - Prob. 8.30QPCh. 8 - Prob. 8.31QPCh. 8 - Prob. 8.32QPCh. 8 - Prob. 8.33QPCh. 8 - Prob. 8.34QPCh. 8 - Prob. 8.35QPCh. 8 - Prob. 8.36QPCh. 8 - Two elements are in the same group, one following...Ch. 8 - Prob. 8.38QPCh. 8 - Prob. 8.39QPCh. 8 - Prob. 8.40QPCh. 8 - Which of the following orbital diagrams are...Ch. 8 - Which of the following orbital diagrams are...Ch. 8 - Which of the following electron configurations are...Ch. 8 - Choose the electron configurations that are...Ch. 8 - Write all of the possible orbital diagrams for the...Ch. 8 - Prob. 8.46QPCh. 8 - Prob. 8.47QPCh. 8 - Use the building-up principle to obtain the...Ch. 8 - Use the building-up principle to obtain the...Ch. 8 - Give the electron configuration of the ground...Ch. 8 - Barium is a Group 2A element in Period 6. Deduce...Ch. 8 - Bismuth is a Group 5A element in Period 6. Write...Ch. 8 - Tungsten is a Group 6B element in Period 6. What...Ch. 8 - Manganese is a Group 7B element in Period 4. What...Ch. 8 - Thallium has the ground-state configuration...Ch. 8 - The configuration for the ground state of iridium...Ch. 8 - Write the orbital diagram for the ground state of...Ch. 8 - Prob. 8.58QPCh. 8 - Write an orbital diagram for the ground state of...Ch. 8 - Write an orbital diagram for the ground state of...Ch. 8 - Order the following elements by increasing atomic...Ch. 8 - Using periodic trends, arrange the following...Ch. 8 - Using periodic trends, arrange the following...Ch. 8 - Arrange the following elements in order of...Ch. 8 - From what you know in a general way about electron...Ch. 8 - Prob. 8.66QPCh. 8 - If potassium chlorate has the formula KClO3, what...Ch. 8 - Prob. 8.68QPCh. 8 - Write the complete ground-state electron...Ch. 8 - Prob. 8.70QPCh. 8 - Obtain the valence-shell configuration of the...Ch. 8 - Prob. 8.72QPCh. 8 - Write the orbital diagram for the ground state of...Ch. 8 - Prob. 8.74QPCh. 8 - Prob. 8.75QPCh. 8 - Prob. 8.76QPCh. 8 - From Figure 8.18, predict the first ionization...Ch. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - Prob. 8.80QPCh. 8 - Prob. 8.81QPCh. 8 - Match each element on the right with a set of...Ch. 8 - Find the electron configuration of the element...Ch. 8 - Find the electron configuration of the element...Ch. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Prob. 8.87QPCh. 8 - Prob. 8.88QPCh. 8 - Prob. 8.89QPCh. 8 - Prob. 8.90QPCh. 8 - The following are orbital diagrams for presumed...Ch. 8 - Prob. 8.92QPCh. 8 - A metallic element, M, reacts vigorously with...Ch. 8 - A nonmetallic element, R, burns brightly in air to...Ch. 8 - The ground-state electron configuration of an atom...Ch. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - Prob. 8.99QPCh. 8 - A neutral atom has the electron configuration...Ch. 8 - Prob. 8.101QPCh. 8 - A metallic element reacts vigorously with water,...Ch. 8 - Prob. 8.103QPCh. 8 - Prob. 8.104QPCh. 8 - Prob. 8.105QPCh. 8 - Prob. 8.106QPCh. 8 - An atom easily loses two electrons to form the ion...Ch. 8 - Prob. 8.108QPCh. 8 - Prob. 8.109QPCh. 8 - The electron affinity of the lutetium atom...Ch. 8 - Prob. 8.111QPCh. 8 - Prob. 8.112QPCh. 8 - Prob. 8.113QPCh. 8 - Prob. 8.114QPCh. 8 - How much energy would be required to ionize 5.00...Ch. 8 - Prob. 8.116QPCh. 8 - Prob. 8.117QPCh. 8 - Prob. 8.118QPCh. 8 - The lattice energy of an ionic solid such as NaCl...Ch. 8 - Calculate H for the following process:...
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- Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…arrow_forwardPlease correct answer and don't use hand ratingarrow_forward1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)arrow_forward
- What is the pH of the Tris buffer after the addition of 10 mL of 0.01M NaOH? How would I calculate this?arrow_forwardWhy do isopolianions form polymeric species with a defined molecular weight? What does it depend on?arrow_forwardWhat are isopolianions? Describe the structural unit of isopolianions.arrow_forward
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