General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN: 9781305580343
Author: Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher: Cengage Learning
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Question
Chapter 8, Problem 8.111QP
Interpretation Introduction
Interpretation:
The unknown element (E) group has to be identified.
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Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 8 Solutions
General Chemistry - Standalone book (MindTap Course List)
Ch. 8.1 - Look at the following orbital diagrams and...Ch. 8.2 - Imagine a world in which the Pauli principle is No...Ch. 8.3 - Use the building-up principle to obtain the...Ch. 8.3 - Prob. 8.3ECh. 8.3 - Prob. 8.4ECh. 8.3 - Prob. 8.2CCCh. 8.4 - Write an orbital diagram for the ground state of...Ch. 8.6 - Prob. 8.6ECh. 8.6 - The first ionization energy of the chlorine atom...Ch. 8.6 - Prob. 8.8E
Ch. 8.6 - Prob. 8.3CCCh. 8.7 - Prob. 8.4CCCh. 8 - Describe the experiment of Stern and Gerlach. How...Ch. 8 - Prob. 8.2QPCh. 8 - Prob. 8.3QPCh. 8 - What is the maximum number of electrons that can...Ch. 8 - List the orbitals in order of increasing orbital...Ch. 8 - Prob. 8.6QPCh. 8 - Prob. 8.7QPCh. 8 - Prob. 8.8QPCh. 8 - Prob. 8.9QPCh. 8 - Prob. 8.10QPCh. 8 - Describe the major trends that emerge when atomic...Ch. 8 - Prob. 8.12QPCh. 8 - What main group in the periodic table has elements...Ch. 8 - Prob. 8.14QPCh. 8 - Prob. 8.15QPCh. 8 - Prob. 8.16QPCh. 8 - What is the name of the alkali metal atom with...Ch. 8 - What would you predict for the atomic number of...Ch. 8 - Prob. 8.19QPCh. 8 - Prob. 8.20QPCh. 8 - Prob. 8.21QPCh. 8 - Prob. 8.22QPCh. 8 - Prob. 8.23QPCh. 8 - Prob. 8.24QPCh. 8 - Prob. 8.25QPCh. 8 - Which of the following atoms, designated by their...Ch. 8 - Prob. 8.27QPCh. 8 - Prob. 8.28QPCh. 8 - Periodic Properties I A hypothetical element, X,...Ch. 8 - Prob. 8.30QPCh. 8 - Prob. 8.31QPCh. 8 - Prob. 8.32QPCh. 8 - Prob. 8.33QPCh. 8 - Prob. 8.34QPCh. 8 - Prob. 8.35QPCh. 8 - Prob. 8.36QPCh. 8 - Two elements are in the same group, one following...Ch. 8 - Prob. 8.38QPCh. 8 - Prob. 8.39QPCh. 8 - Prob. 8.40QPCh. 8 - Which of the following orbital diagrams are...Ch. 8 - Which of the following orbital diagrams are...Ch. 8 - Which of the following electron configurations are...Ch. 8 - Choose the electron configurations that are...Ch. 8 - Write all of the possible orbital diagrams for the...Ch. 8 - Prob. 8.46QPCh. 8 - Prob. 8.47QPCh. 8 - Use the building-up principle to obtain the...Ch. 8 - Use the building-up principle to obtain the...Ch. 8 - Give the electron configuration of the ground...Ch. 8 - Barium is a Group 2A element in Period 6. Deduce...Ch. 8 - Bismuth is a Group 5A element in Period 6. Write...Ch. 8 - Tungsten is a Group 6B element in Period 6. What...Ch. 8 - Manganese is a Group 7B element in Period 4. What...Ch. 8 - Thallium has the ground-state configuration...Ch. 8 - The configuration for the ground state of iridium...Ch. 8 - Write the orbital diagram for the ground state of...Ch. 8 - Prob. 8.58QPCh. 8 - Write an orbital diagram for the ground state of...Ch. 8 - Write an orbital diagram for the ground state of...Ch. 8 - Order the following elements by increasing atomic...Ch. 8 - Using periodic trends, arrange the following...Ch. 8 - Using periodic trends, arrange the following...Ch. 8 - Arrange the following elements in order of...Ch. 8 - From what you know in a general way about electron...Ch. 8 - Prob. 8.66QPCh. 8 - If potassium chlorate has the formula KClO3, what...Ch. 8 - Prob. 8.68QPCh. 8 - Write the complete ground-state electron...Ch. 8 - Prob. 8.70QPCh. 8 - Obtain the valence-shell configuration of the...Ch. 8 - Prob. 8.72QPCh. 8 - Write the orbital diagram for the ground state of...Ch. 8 - Prob. 8.74QPCh. 8 - Prob. 8.75QPCh. 8 - Prob. 8.76QPCh. 8 - From Figure 8.18, predict the first ionization...Ch. 8 - Prob. 8.78QPCh. 8 - Prob. 8.79QPCh. 8 - Prob. 8.80QPCh. 8 - Prob. 8.81QPCh. 8 - Match each element on the right with a set of...Ch. 8 - Find the electron configuration of the element...Ch. 8 - Find the electron configuration of the element...Ch. 8 - Prob. 8.85QPCh. 8 - Prob. 8.86QPCh. 8 - Prob. 8.87QPCh. 8 - Prob. 8.88QPCh. 8 - Prob. 8.89QPCh. 8 - Prob. 8.90QPCh. 8 - The following are orbital diagrams for presumed...Ch. 8 - Prob. 8.92QPCh. 8 - A metallic element, M, reacts vigorously with...Ch. 8 - A nonmetallic element, R, burns brightly in air to...Ch. 8 - The ground-state electron configuration of an atom...Ch. 8 - Prob. 8.96QPCh. 8 - Prob. 8.97QPCh. 8 - Prob. 8.98QPCh. 8 - Prob. 8.99QPCh. 8 - A neutral atom has the electron configuration...Ch. 8 - Prob. 8.101QPCh. 8 - A metallic element reacts vigorously with water,...Ch. 8 - Prob. 8.103QPCh. 8 - Prob. 8.104QPCh. 8 - Prob. 8.105QPCh. 8 - Prob. 8.106QPCh. 8 - An atom easily loses two electrons to form the ion...Ch. 8 - Prob. 8.108QPCh. 8 - Prob. 8.109QPCh. 8 - The electron affinity of the lutetium atom...Ch. 8 - Prob. 8.111QPCh. 8 - Prob. 8.112QPCh. 8 - Prob. 8.113QPCh. 8 - Prob. 8.114QPCh. 8 - How much energy would be required to ionize 5.00...Ch. 8 - Prob. 8.116QPCh. 8 - Prob. 8.117QPCh. 8 - Prob. 8.118QPCh. 8 - The lattice energy of an ionic solid such as NaCl...Ch. 8 - Calculate H for the following process:...
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