The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted. Concept Introduction: Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds. Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Question

21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to most acidic). OH OH SH NH2 8 NH3 OH (b) OH OH OH (c) & & & CH3 NO2 21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol. OH OH OH OH PK 10.0 PK 8.81 PK 9.28 PK 9.81

Answer 1

Question

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

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21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to most acidic). OH OH SH NH2 8 NH3 OH (b) OH OH OH (c) & & & CH3 NO2 21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol. OH OH OH OH PK 10.0 PK 8.81 PK 9.28 PK 9.81

identify which spectrum is for acetaminophen and which is for phenacetin

The Concept of Aromaticity 21.15 State the number of 2p orbital electrons in each molecule or ion. (a) (b) (e) (f) (c) (d) (h) (i) DA (k) 21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the Hückel criteria? Which, if planar, would be antiaromatic? 21.17 Which of the following structures are considered aromatic according to the Hückel criteria? ---0-0 (a) (b) (c) (d) (e) (h) H -H .8.0- 21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a heteroatom?

Answer 2

Question

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

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Answer 3

Question

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

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Answer 4

Question

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

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Answer 5

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 6

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 7

Chapter 8.1, Problem 1P

(a)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 8

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 9

b)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 10

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 11

c)

Interpretation Introduction

Interpretation:

The possibilities of different mono- and di-substuituted compounds for the given two compounds has to be predicted.

Concept Introduction:

Disubstituted compounds: By replacing two hydrogens and replacing with the some other two atoms gives rise to disubstituted compounds.

Monosubstituted compounds: By replacing a hydrogen from the given compound with other atom gives rise to possible number of monosubstituted compounds.

Answer 12

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Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

Solution Summary: The author explains the possibilities of different mono- and di-substuituted compounds for the given two compounds.

Chapter 8 Solutions