The diene and dienophile from the given compounds has to be predicted. Concept Introduction: Diels-Alder reaction: A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product. Conformation of Diene: S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer. S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer. Condition for Diels-Alder reaction: The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

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Answer 1

Question

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

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Answer 2

Question

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

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Answer 3

Question

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

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Answer 4

Question

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

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Answer 5

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 6

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 7

Chapter 8.15, Problem 47P

a)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 8

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 9

b)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 10

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 11

c)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 12

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 13

d)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 14

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 15

e)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 16

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 17

f)

Interpretation Introduction

Interpretation: The diene and dienophile from the given compounds has to be predicted.

Concept Introduction:

Diels-Alder reaction:

A conjugated diene reacts with a compound containing a carbon-carbon double bond. It is a cycloaddition reaction, where two reactants form a cyclic product.

Conformation of Diene:

S-Cis Conformer: The double bonds are cis about the single bond (s stands for single), in an s-cis conformer.

S-trans Conformer: The double bonds are trans- about the single bond (s stands for single) in an s-trans conformer.

Condition for Diels-Alder reaction:

The conjugate diene must be in an s-cis conformation because when it is in an S-trans conformation, C-1 and C-4 are too far apart to react with the dienophile in a concerted reaction.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 8.1 - Prob. 1P Ch. 8.1 - Prob. 2P Ch. 8.4 - Prob. 3P Ch. 8.5 - Prob. 4P Ch. 8.5 - Prob. 6P Ch. 8.6 - a. Predict the relative bond lengths of the three...Ch. 8.6 - Prob. 8P Ch. 8.6 - Prob. 9P Ch. 8.6 - Prob. 10P Ch. 8.7 - Prob. 11P

Solution Summary: The author explains Diels-Alder reaction, where two reactants form a cyclic product.

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Chapter 8 Solutions