Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
Question
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Chapter 8, Problem 8.9NP

(a)

Interpretation Introduction

Interpretation:The denser substance out of graphite and diamond needs to be determined on the basis of given P-T curve.

  Physical Chemistry, Chapter 8, Problem 8.9NP , additional homework tip  1

Concept Introduction:All substances can mainly exist in three phases; solid, liquid and gas. These three phases can convert into each other by the application of temperature and pressure such as heating of solid leads to the conversion to liquid and then gaseous state of matter.

Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram.

(b)

Interpretation Introduction

Interpretation:Themore denser substance out of graphite and liquid carbon needs to be determined on the basis of given P-T curve.

  Physical Chemistry, Chapter 8, Problem 8.9NP , additional homework tip  2

Concept Introduction:All substances can mainly exist in three phases; solid, liquid and gas. These three phases can convert into each other by the application of temperature and pressure such as heating of solid leads to the conversion to liquid and then gaseous state of matter.

Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram.

(c)

Interpretation Introduction

Interpretation:The reason of presence of two triple points needs to be explained in the P-T curve for carbon.

  Physical Chemistry, Chapter 8, Problem 8.9NP , additional homework tip  3

Concept Introduction:All substances can mainly exist in three phases; solid, liquid and gas. These three phases can convert into each other by the application of temperature and pressure such as heating of solid leads to the conversion to liquid and then gaseous state of matter.

Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram.

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