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(a)
Interpretation: The phase diagram of NH3needs to be drawn from the given data and the phases at 195.41 K and 9506 Pa pressure needs to be determined.
Concept Introduction: All substances can mainly exist in three phases; solid, liquid and gases. These three phases can convert into each other by the application of temperature and pressure such as by heating of solid, it converts to liquid and then gaseous
Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram. A triple point indicates the value of T and P at which all the three phases of a substance that is pressure, temperature and volume coexist. At this point, the fusion, sublimation and vaporization curve intersect each other.
(b)
Interpretation: The phase of ammonia at 195.41 K and 6077 Pa pressure needs to be determined.
Concept Introduction: All substances can mainly exist in three phases; solid, liquid and gases. These three phases can convert into each other by the application of temperature and pressure such as by heating of solid, it converts to liquid and then gaseous state of matter.
Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram. A triple point indicates the value of T and P at which all the three phases of a substance that is pressure, temperature and volume coexist. At this point, the fusion, sublimation and vaporization curve intersect each other.(c)
Interpretation: The phase of NH3at 245.45 K and 101325 Pa pressure needs to be determined.
Concept Introduction: All substances can mainly exist in three phases; solid, liquid and gases. These three phases can convert into each other by the application of temperature and pressure such as by heating of solid, it converts to liquid and then gaseous state of matter.
Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram. A triple point indicates the value of T and P at which all the three phases of a substance that is pressure, temperature and volume coexist. At this point, the fusion, sublimation and vaporization curve intersect each other.
(d)
Interpretation: The phase of NH3at 415 K and
Concept Introduction: All substances can mainly exist in three phases; solid, liquid and gases. These three phases can convert into each other by the application of temperature and pressure such as by heating of solid, it converts to liquid and then gaseous state of matter.
Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram. A triple point indicates the value of T and P at which all the three phases of a substance that is pressure, temperature and volume coexist. At this point, the fusion, sublimation and vaporization curve intersect each other.
(e)
Interpretation: The phase of NH3at 185.5 K and 6077 Pa pressure needs to be determined.
Concept Introduction: All substances can mainly exist in three phases; solid, liquid and gases. These three phases can convert into each other by the application of temperature and pressure such as by heating of solid, it converts to liquid and then gaseous state of matter.
Similarly, the gases can be compressed at high pressure to liquefy. The interconversion of three phases of substance can be shown on the phase diagram. A triple point indicates the value of T and P at which all the three phases of a substance that is pressure, temperature and volume coexist. At this point, the fusion, sublimation and vaporization curve intersect each other.
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Chapter 8 Solutions
Physical Chemistry
- Basic strength of organic bases.arrow_forwardNucleophilic Aromatic Substitution: What is the product of the reaction? What is the name of the intermediate complex? *See imagearrow_forwardPredict the final product. If 2 products are made, list which should be “major” and “minor” *see attachedarrow_forward
- Nucleophilic Aromatic Substitution: What is the product of the reaction? *see imagearrow_forwardShow the correct sequence to connect the reagent to product. * see imagearrow_forwardThe answer here says that F and K have a singlet and a doublet. The singlet and doublet are referring to the H's 1 carbon away from the carbon attached to the OH. Why don't the H's two carbons away, the ones on the cyclohexane ring, cause more peaks on the signal?arrow_forward
- Draw the Birch Reduction for this aromatic compound and include electron withdrawing groups and electron donating groups. *See attachedarrow_forwardShow the correct sequence to connect the reagent to product. * see imagearrow_forwardBlocking Group are use to put 2 large sterically repulsive group ortho. Show the correct sequence toconnect the reagent to product with the highest yield possible. * see imagearrow_forward
- Elimination-Addition: What molecule was determined to be an intermediate based on a “trapping experiment”? *please solve and see imagearrow_forwardShow the correct sequence to connect the reagent to product. * see imagearrow_forwardPredict the final product. If 2 products are made, list which should be “major” and “minor”. **see attachedarrow_forward
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