Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 8, Problem 8.14CP
Interpretation Introduction
Interpretation:The reason for a triple point in a P-T diagram to becomea triple line in a P-V diagram needs to be explained.
Concept introduction:
P-T diagram refers to a display of stability of regions for a pure substance as a function of pressure and temperature.
P-V diagram refers to a diagram that can be used to describe the corresponding changes in pressure and volume of the system.
Critical point value is referred to as the point in which gaseous and liquid phases of a substance initially become indistinguishable from one another since both forms have the same density.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 8 Solutions
Physical Chemistry
Ch. 8 - Prob. 8.1CPCh. 8 - Prob. 8.2CPCh. 8 - Prob. 8.3CPCh. 8 - Prob. 8.4CPCh. 8 - Prob. 8.5CPCh. 8 - Prob. 8.6CPCh. 8 - Prob. 8.7CPCh. 8 - Prob. 8.8CPCh. 8 - Prob. 8.9CPCh. 8 - Prob. 8.10CP
Ch. 8 - Prob. 8.11CPCh. 8 - Prob. 8.12CPCh. 8 - Prob. 8.13CPCh. 8 - Prob. 8.14CPCh. 8 - Prob. 8.15CPCh. 8 - Prob. 8.16CPCh. 8 - Prob. 8.17CPCh. 8 - Prob. 8.18CPCh. 8 - Prob. 8.19CPCh. 8 - Prob. 8.20CPCh. 8 - Prob. 8.21CPCh. 8 - Prob. 8.1NPCh. 8 - Prob. 8.2NPCh. 8 - Prob. 8.3NPCh. 8 - Prob. 8.4NPCh. 8 - Prob. 8.5NPCh. 8 - Prob. 8.6NPCh. 8 - Prob. 8.7NPCh. 8 - Prob. 8.8NPCh. 8 - Prob. 8.9NPCh. 8 - Prob. 8.10NPCh. 8 - Prob. 8.11NPCh. 8 - Prob. 8.12NPCh. 8 - Prob. 8.13NPCh. 8 - Prob. 8.14NPCh. 8 - Prob. 8.15NPCh. 8 - Prob. 8.16NPCh. 8 - Prob. 8.17NPCh. 8 - Prob. 8.18NPCh. 8 - Prob. 8.20NPCh. 8 - Prob. 8.21NPCh. 8 - Prob. 8.22NPCh. 8 - Prob. 8.23NPCh. 8 - Prob. 8.24NPCh. 8 - Prob. 8.25NPCh. 8 - Prob. 8.26NPCh. 8 - Prob. 8.27NPCh. 8 - Prob. 8.28NPCh. 8 - Prob. 8.29NPCh. 8 - Prob. 8.30NPCh. 8 - Prob. 8.31NPCh. 8 - Prob. 8.32NPCh. 8 - Prob. 8.33NPCh. 8 - Prob. 8.34NPCh. 8 - Prob. 8.35NPCh. 8 - Prob. 8.36NPCh. 8 - Prob. 8.37NPCh. 8 - Prob. 8.38NPCh. 8 - Prob. 8.39NPCh. 8 - Prob. 8.40NPCh. 8 - Prob. 8.41NPCh. 8 - Prob. 8.42NPCh. 8 - Prob. 8.43NPCh. 8 - Prob. 8.44NPCh. 8 - Prob. 8.45NP
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