Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 8, Problem 89IL
You are doing an experiment in the laboratory and want to prepare a solution in a polar solvent. Which solvent would you choose, methanol (CH3OH) or toluene (C6H5CH3)? Explain your choice.
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Chapter 8 Solutions
Chemistry & Chemical Reactivity
Ch. 8.2 - Draw Lewis electron dot structures for CH3Cl...Ch. 8.2 - Prob. 2CYUCh. 8.2 - Prob. 3CYUCh. 8.2 - Prob. 4CYUCh. 8.2 - Prob. 1RCCh. 8.2 - 2. Which one of the species in the list below is...Ch. 8.2 - Prob. 3RCCh. 8.2 - Prob. 4RCCh. 8.3 - Prob. 1CYUCh. 8.3 - 1. What is the formal charge of the P atom in the...
Ch. 8.4 - Draw resonance structures for the bicarbonate ion,...Ch. 8.4 - 1. For which of the following species, SO32−, NO+,...Ch. 8.4 - Prob. 2RCCh. 8.5 - Sketch the Lewis structures for CIF2+ and CIF2....Ch. 8.5 - Prob. 1QCh. 8.5 - Prob. 2QCh. 8.5 - Prob. 1RCCh. 8.5 - Prob. 2RCCh. 8.6 - What is the shape of the dichloromethane (CH2C12)...Ch. 8.6 - Give the electron-pair geometry and molecular...Ch. 8.6 - Draw the Lewis structure for lCl2, and then decide...Ch. 8.6 - Prob. 4CYUCh. 8.6 - Which of the following species has...Ch. 8.6 - Prob. 2RCCh. 8.6 - What is the approximate ClCCl bond angle in...Ch. 8.6 - 4. What is the molecular geometry of N2O (where...Ch. 8.7 - Draw the resonance structures for SCN. What are...Ch. 8.7 - For each of the following molecules, decide...Ch. 8.7 - Prob. 1RCCh. 8.7 - 2. Which of the following best describes the...Ch. 8.7 - Three resonance forms can be drawn for the...Ch. 8.8 - The electrostatic potential surface for SOCl2 is...Ch. 8.8 - Using the bond dissociation enthalpies in Table...Ch. 8.8 - Prob. 1RCCh. 8.8 - Prob. 2RCCh. 8.9 - 1. Which of the following species has the longest...Ch. 8.9 - 2. Which of the following species has the largest...Ch. 8.9 - 3. Use bond dissociation enthalpies to estimate...Ch. 8 - Give the periodic group number and number of...Ch. 8 - Give the periodic group number and number of...Ch. 8 - For elements in Groups 4A-7A of the periodic...Ch. 8 - Prob. 4PSCh. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Show all possible resonance structures for each of...Ch. 8 - Show all possible resonance structures for each of...Ch. 8 - Prob. 11PSCh. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Determine the formal charge on each atom in the...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Prob. 18PSCh. 8 - Prob. 19PSCh. 8 - The following molecules or ions all have three...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Draw a Lewis structure for each of the following...Ch. 8 - Give approximate values for the indicated bond...Ch. 8 - Give approximate values for the indicated bond...Ch. 8 - Phenylalanine is one of the natural amino acids...Ch. 8 - Acetylacetone has the structure shown here....Ch. 8 - For each pair of bonds, indicate the more polar...Ch. 8 - For each of the bonds listed below, tell which...Ch. 8 - Urea, (NH2)2CO, is used in plastics and...Ch. 8 - Considering both formal charges and bond...Ch. 8 - Considering both formal charge and bond...Ch. 8 - Three resonance structures are possible for...Ch. 8 - Three resonance structures are possible for the...Ch. 8 - Compare the electron dot structures of the...Ch. 8 - Compare the electron dot structures of the...Ch. 8 - The chemistry of the nitrite ion and HNO2: (a) Two...Ch. 8 - Draw the resonance structures for the formate ion,...Ch. 8 - Prob. 39PSCh. 8 - Consider the following molecules: (a) CH4 (b)...Ch. 8 - Which of the following molecules is(are) polar?...Ch. 8 - Prob. 42PSCh. 8 - Give the bond order for each bond in the following...Ch. 8 - Prob. 44PSCh. 8 - In each pair of bonds, predict which is shorter....Ch. 8 - In each pair of bonds, predict which is shorter....Ch. 8 - Prob. 47PSCh. 8 - Compare the carbon-oxygen bond lengths in the...Ch. 8 - Consider the carbon-oxygen bond in formaldehyde...Ch. 8 - Compare the nitrogen-nitrogen bond in hydrazine,...Ch. 8 - Ethanol can be made by the reaction of ethylene...Ch. 8 - Methanol can be made by partial oxidation of...Ch. 8 - Hydrogenation reactions, which involve the...Ch. 8 - Phosgene, Cl2CO, is a highly toxic gas that was...Ch. 8 - The compound oxygen difluoride is quite reactive,...Ch. 8 - Oxygen atoms can combine with ozone to form...Ch. 8 - Prob. 57GQCh. 8 - Prob. 58GQCh. 8 - Which of the following compounds or ions do not...Ch. 8 - Prob. 60GQCh. 8 - Draw resonance structures for the formate ion,...Ch. 8 - Prob. 62GQCh. 8 - Prob. 63GQCh. 8 - What is the principle of electroneutrality? Use...Ch. 8 - Prob. 65GQCh. 8 - Draw resonance structures for the SO2 molecule,...Ch. 8 - What are the orders of the NO bonds in NO2 and...Ch. 8 - Which has the greater ONO bond angle, NO2 or NO2+?...Ch. 8 - Compare the FClF angles in CIF2+ and ClF2. Using...Ch. 8 - Draw an electron dot structure for the cyanide...Ch. 8 - Draw the electron dot structure for the sulfite...Ch. 8 - Dinitrogen monoxide, N2O, can decompose to...Ch. 8 - The equation for the combustion of gaseous...Ch. 8 - The cyanate ion, OCN, has the least...Ch. 8 - Vanillin is the flavoring agent in vanilla extract...Ch. 8 - Explain why (a) XeF2 has a linear molecular...Ch. 8 - The formula for nitryl chloride is ClNO2 (in which...Ch. 8 - Hydroxyproline is a less-common amino acid. (a)...Ch. 8 - Amides are an important class of organic...Ch. 8 - Prob. 81GQCh. 8 - The molecule shown here. 2-furylmelhanethiol, is...Ch. 8 - Dihydroxyacetone is a component of quick-tanning...Ch. 8 - It is possible to draw three resonance structures...Ch. 8 - Acrolein is used to make plastics. Suppose this...Ch. 8 - Molecules in space: (a) In addition to molecules...Ch. 8 - 1,2-Dichloroethylene can be synthesized by adding...Ch. 8 - The molecule pictured below is epinephrine, a...Ch. 8 - You are doing an experiment in the laboratory and...Ch. 8 - Prob. 90ILCh. 8 - A paper published in the research Journal Science...Ch. 8 - Uracil is one of the bases in RNA, a close...Ch. 8 - Prob. 93SCQCh. 8 - Prob. 94SCQCh. 8 - Bromine-containing species play a role in...Ch. 8 - Acrylamide, H2C=CHCONH2, is a known neurotoxin and...
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- In addition to CO, CO2, and C3O2, there is another molecular oxide of carbon, pentacarbon dioxide, C5O2, a yellow solid. (a) What is the approximate C-to-C-to-O bond angle in pentacarbon dioxide? (b) What is the approximate C-to-C-to-C bond angle in this compound?arrow_forwardDraw the lewis structure for CO2 and H2O showing the correct bond angles. Indicate the direction of polarity of the bonds on each molecule. Which molecule is polar. Explain your choice.arrow_forwardDraw the 2D and the 3D Lewis structure for each molecule. You do not need to show resonance structures here. Determine the electron pair geometry (EPG), the molecular geometry (MG), the bond angle (BA) around the central atom, and the hybridization of the central or bold atom. Circle the formula of any polar molecule. For molecules with more than one central atom (e.g. CHCH20H) give the structure around the bold atom.arrow_forward
- Draw the Lewis structures for each compound and then identify which one is polar. CH₂O CO₂ C₂H4 C2H2arrow_forwardDraw the Lewis structure of C2H4CI2 (both Cl atoms on one C atom) and then determine if the molecule is polar or nonpolar.arrow_forwardSilicones are polymeric compounds containing, among others, the following types of covalent bonds: Si–O, Si–C, C–H, and C–C. Using the electronegativity values as shown, arrange the bonds in order of increasing polarity and designate the positive and negative atoms using the symbols δ+ and δ–.arrow_forward
- Designate the structural features of polar molecules using partial charges or arrows. Ethyl heptanoate is responsible for grape aroma. It has the chemical formula C9H1802 but structural formula CH3-(CH2)s-COO-CH2-CH3. A structure is shown below. Which bonds would feature partial charges? Designate them using partial charges or arrows. H H H | H H H Harrow_forwardCyanogen has the formula C2N2. Propose a bonding scheme that gives each atom the correct number of covalent bonds. (Hint: the two carbon atoms are in the center of a linear molecule.)arrow_forwardWrite the Lewis structure for the following molecule. State the electronic structure (shape based on electron pairs or bonds) AND the geometric structure (shape based on the atoms only). Include all valence electrons in your structure. State how many electrons are used to form covalent bonds in the molecule. Is the molecule polar? H_2Sarrow_forward
- 2. From the models of SF4, BrF3, and XeF4, deduce whether different atom arrangement, called geometrical isomers, are possible; if so, sketch them below. Indicate the preferred geometry for each case and suggest a reason for your choice. Indicate which structures have dipole moments and show their direction, Preferred Molecular Compound Electron Dipole Reason Geometry Moment (Polarity) geometry SF4 BRF3 XeF4 3. Using the Lewis structure predict the geometrical structures of the following ions and state the hybridization of the central atom. Ion Electron Geometry Molecular Formal Charge Central Atom Geometry of Central Hybridization Atom CO32- NO3- BF4arrow_forwardI am struggling to understand the bond angles between the atoms of the molecule O=N-Cl. The solutions state that the angle is 113°, but I am confused as to why it is not 120°arrow_forwardDraw the 2D and the 3D Lewis structure for each molecule. You do not need to show resonance structures here. Determine the electron pair geometry (EPG), the molecular geometry (MG), the bond angle (BA) around the central atom, and the hybridization of the central or bold atom. Circle the formula of any polar molecule. For molecules with more than one central atom (e.g. CH3CH20H) give the structure around the bold atom. Molecule ЕPG Hyb (circle if 2D Lewis Structure 3D Lewis Structure MG polar) ВА CH2S GeO2 CF4arrow_forward
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