CHEMISTRY: THE MOLECULAR NATURE OF MATTE
CHEMISTRY: THE MOLECULAR NATURE OF MATTE
9th Edition
ISBN: 9781265197773
Author: SILBERBERG
Publisher: MCG
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Chapter 8, Problem 8.87P

(a)

Interpretation Introduction

Interpretation:

Li+, K+ and Na+ are to be arranged in the order of increasing size.

Concept introduction:

The cation is an ionic species with a positive charge. It has more protons as compared to electrons so the net charge on the cations is positive. Its symbol is the element with a superscript of the positive charge.

The anion is an ionic species with a negative charge. It has more electrons than protons so the net charge on the anions is negative. Its symbol is the element with a superscript of the negative charge.

In general, cations are smaller than anions because the number of shells decreases after the loss of electrons in case of cations.

In the case of isoelectronic species, the size of cations decreases with an increase in positive charge and size of anion increases with an increase in a negative charge.

(b)

Interpretation Introduction

Interpretation:

Se2, Rb+ and Br are to be arranged in the order of the increasing size.

Concept introduction:

The cation is an ionic species with a positive charge. It has more protons as compared to electrons so the net charge on the cations is positive. Its symbol is the element with a superscript of the positive charge.

The anion is an ionic species with a negative charge. It has more electrons than protons so the net charge on the anions is negative. Its symbol is the element with a superscript of the negative charge.

In general, cations are smaller than anions because the number of shells decreases after the loss of electrons in case of cations.

In the case of isoelectronic species, the size of cations decreases with an increase in positive charge and size of anion increases with an increase in a negative charge.

(c)

Interpretation Introduction

Interpretation:

O2, F and N3 are to be arranged in the order of the increasing size.

Concept introduction:

The cation is an ionic species with a positive charge. It has more protons as compared to electrons so the net charge on the cations is positive. Its symbol is the element with a superscript of the positive charge.

The anion is an ionic species with a negative charge. It has more electrons than protons so the net charge on the anions is negative. Its symbol is the element with a superscript of the negative charge.

Cations are smaller than anions because the number of shells decreases after the loss of electrons in case of cations.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 8 Solutions

CHEMISTRY: THE MOLECULAR NATURE OF MATTE

Ch. 8.4 - Prob. 8.6AFPCh. 8.4 - Prob. 8.6BFPCh. 8.4 - Prob. 8.7AFPCh. 8.4 - Prob. 8.7BFPCh. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - To test Döbereiner’s idea (Problem 8.3),...Ch. 8 - Summarize the rules for the allowable values of...Ch. 8 - Prob. 8.6PCh. 8 - State the exclusion principle. What does it imply...Ch. 8 - What is the key distinction between sublevel...Ch. 8 - Prob. 8.9PCh. 8 - Prob. 8.10PCh. 8 - Prob. 8.11PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.13PCh. 8 - How many electrons in an atom can have each of the...Ch. 8 - Prob. 8.15PCh. 8 - State Hund’s rule in your own words, and show its...Ch. 8 - Prob. 8.17PCh. 8 - For main-group elements, are outer electron...Ch. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Write the full ground-state electron configuration...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.29PCh. 8 - Draw a partial (valence-level) orbital diagram,...Ch. 8 - Draw the partial (valence-level) orbital diagram,...Ch. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - How many inner, outer, and valence electrons are...Ch. 8 - How many inner, outer, and valence electrons are...Ch. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - If the exact outer limit of an isolated atom...Ch. 8 - Given the following partial (valence-level)...Ch. 8 - In what region of the periodic table will you find...Ch. 8 - Why do successive IEs of a given element always...Ch. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - What is a pseudo-noble gas configuration? Give an...Ch. 8 - How are measurements of paramagnetism used to...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - Prob. 8.79PCh. 8 - Prob. 8.80PCh. 8 - Which of these atoms are paramagnetic in their...Ch. 8 - Prob. 8.82PCh. 8 - Prob. 8.83PCh. 8 - Write the condensed ground-state electron...Ch. 8 - Prob. 8.85PCh. 8 - Prob. 8.86PCh. 8 - Rank the ions in each set in order of increasing...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - A fundamental relationship of electrostatics...Ch. 8 - Prob. 8.93PCh. 8 - Prob. 8.94PCh. 8 - Prob. 8.95PCh. 8 - Prob. 8.96PCh. 8 - Prob. 8.97PCh. 8 - Prob. 8.98PCh. 8 - Use Figure 8.16, to find: (a) the longest...Ch. 8 - Prob. 8.100PCh. 8 - Prob. 8.101PCh. 8 - Prob. 8.102P
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