EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
EBK ELEMENTARY PRINCIPLES OF CHEMICAL P
4th Edition
ISBN: 9781119192107
Author: BULLARD
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Chapter 8, Problem 8.71P

A liquid is placed in a wcll-insulatcd container, which is then scaled. Initially, the container and its contents (the liquid and pure nitrogen) are at 93°C and 1 atm; the liquid volume is 70cm3, and the gas volume is 3.00 L. The liquid partially evaporates, and the system cools down and eventually comes to thermal equilibrium at 85°C with liquid still present. Physical property data for the liquid and its vapor are:

   Δ U ^ v = 20 k c a l / m o l a t 90 ° C ( C p ) l i q = 20 c a l / m o l ° C ( C p ) v a p = 10 c a l / ( m o l ° C ) ( S G ) l i q = 0.90 M W = 42

Determine ( C v ) l i q and ( C v ) v a p

  1. (See Equations 8.3-11 and 8.3-12.)
  2. Draw and label a flowchart for this closed system process, and write and simplify the energy balance equation, assuming adiabatic operation.

  • Use the energy balance to calculate the mass of liquid that evaporates, taking 4.97 cal/(mol·°C) as the heat capacity of nitrogen.
  • Calculate the vapor pressure of the liquid at 85°C, assuming that the gas volume remains constant at 3.00 L.
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    Problem 10.18 A 60° set-square has the shortest edge of 40 mm lying in the V.P. The surface is in- clined to the V.P. and perpendicular to the H.P. such that the front view appears as an isosceles triangle. Draw the projections of the set-square and determine its inclination with the V.P. Construction Refer to Fig. 10.18. A 60° set-square inclined to the V.P. and per- pendicular to the H.P. can appear as an isosceles triangle in the front view, when the shorter edge is in the V.P. 1. First stage Draw a right angled triangle 40 a' a' b' c' b' X 40 C' a,b C a,b a'b'c' keeping 40 mm long a'b' perpen- dicular to xy. Project the corners to xy and obtain ac as the top view. 2. Second stage Draw another right angled triangle a'b'c' on the horizontal locus line from points a', b' and c' of the first stage such that length of b'c' is equal to that of a'b'. Project a'b' to meet xy at ab. Draw an arc with centre a and radius equal to ac of the first stage to meet the vertical projector of c' at…
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    TL = 85 D. Problem 9.12 The top view of a line measures 60 mm. The line is parallel to the V.P. and inclined at 45° to the H.P. One end of the line is 25 mm in front of the V.P. and lies on the H.P. Draw its projections and determine the true length. Interpretation Let the line be PQ parallel to the V.P. The front view has true length and the top view is parallel to xy. Construction Refer to Fig. 9.12. 1. Draw a reference line xy. Mark point p' on xy and point p 25 mm below xy. 2. Draw a 60 mm long line pq parallel to xy. This repre- sents the top view. 3. Draw line from point p', inclined at 45° to xy to meet the projector from point q at point q'. Join p'a' to represent the front view. Measure length of p'a' as true length of line PQ. Here T.L. = 85 mm. Result True length of line PQ is p'q' = 85 mm. 5 Fig. 9.12 p 60 σ

    Chapter 8 Solutions

    EBK ELEMENTARY PRINCIPLES OF CHEMICAL P

    Ch. 8 - Chlorine gas is to be heated front 120°C and 1 atm...Ch. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Use the enthalpy function of APEx to calculate...Ch. 8 - A stream of carbon monoxide flowing at 300 kg/min...Ch. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Calculate the heat transfer (kJ) required to cool...Ch. 8 - Twenty liters of liquid n-propyl benzoate...Ch. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - A fuel gas containing 95 mole% methane and the...Ch. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Ever wonder why espresso costs much more per cup...Ch. 8 - Prob. 8.31PCh. 8 - Saturated steam at 300°C is used to heat a...Ch. 8 - Pure ethane is burned completely with preheated...Ch. 8 - An adiabatic membrane separation unit is used to...Ch. 8 - A gas containing water vapor has a dry-basis...Ch. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - In the manufacture of nitric acid, ammonia and...Ch. 8 - A natural gas containing 95 mole% methane and the...Ch. 8 - The heat capacity at constant pressure of a gas is...Ch. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - Calculate the heat of vaporization of water...Ch. 8 - Polyvinylpyrrolidone (PVP) is a polymer product...Ch. 8 - Benzene vapor at 480°C is cooled and converted to...Ch. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - A stream of pure cyclopentane vapor flowing at a...Ch. 8 - Prob. 8.55PCh. 8 - Prob. 8.57PCh. 8 - A gas stream containing n-hexane in nitrogen with...Ch. 8 - A mixture of n-hexane vapor and air leaves a...Ch. 8 - An equimolar liquid mixture of n-pentane and...Ch. 8 - A liquid stream containing 50.0 mole% benzene and...Ch. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - Prob. 8.66PCh. 8 - An aqueous slurry at 30°C containing 20.0 wt%...Ch. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - A liquid is placed in a wcll-insulatcd container,...Ch. 8 - A small pharmaceutical firm plans to manufacture a...Ch. 8 - Freeze drying is a technique for dehydrating...Ch. 8 - The manufacturers of a new oatmeal product want to...Ch. 8 - Freeze concentration is used to produce a...Ch. 8 - A mixture containing 35.0 mole% n-butane and the...Ch. 8 - A liquid mixture of benzene and toluene containing...Ch. 8 - Prob. 8.79PCh. 8 - An outside-air sample is taken on a day when the...Ch. 8 - Prob. 8.83PCh. 8 - Prob. 8.84PCh. 8 - Prob. 8.85PCh. 8 - Wet solids pass through a continuous dryer. Hot...Ch. 8 - Prob. 8.88PCh. 8 - Prob. 8.93PCh. 8 - The heat of solution of ammonia in water at 1 atm...Ch. 8 - Prob. 8.96PCh. 8 - Sodium hydroxide is dissolved in enough water to...Ch. 8 - A sulfuric acid solution is labeled 8 N (where 1 N...Ch. 8 - You are about to dilute 2.00 mol of 100% sulfuric...Ch. 8 - Prob. 8.100PCh. 8 - A 0.1 mole% caustic soda (NaOH) solution is to be...Ch. 8 - Prob. 8.102PCh. 8 - Ortho-phosphoric acid (H3PO4) is produced as a...Ch. 8 - Prob. 8.104PCh. 8 - Fifty milliliters of 100% H2SO4 at 25°C and 84.2...Ch. 8 - Prob. 8.106PCh. 8 - One g-mole of pure liquid sulfuric acid at...Ch. 8 - Prob. 8.108PCh. 8 - Prob. 8.110PCh. 8 - Prob. 8.111PCh. 8 - Taking as references pure liquid sulfuric acid at...Ch. 8 - Prob. 8.113PCh. 8 - An NH3-H2O mixture containing 60wt% NH3 is brought...Ch. 8 - Prob. 8.115P
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