You are asked to manufacture 10 kg of polyester with a number-average molecular weight of 1000 by polymerizing butane-1,4-diol(HO(CH2)4OH) with adipic acid (HOOC-(CH2)4-COOH).a) What weight of diol and diacid do you need, respectively? To whatextent, p, should the reaction be carried out to? Assume a stoichiometricbalance.b) What are the number and weight fractions of dimer, trimer and tetramerat this point in the reaction?c) Because of the polymerization by dehydration to olefin, 3 mol% of thediol will be lost. What would be the number-average molecular weightwhen the reaction is carried out to the same extent? How could you offsetthis loss so that the desired molecular weight
You are asked to manufacture 10 kg of polyester with a number-average molecular weight of 1000 by polymerizing butane-1,4-diol(HO(CH2)4OH) with adipic acid (HOOC-(CH2)4-COOH).a) What weight of diol and diacid do you need, respectively? To whatextent, p, should the reaction be carried out to? Assume a stoichiometricbalance.b) What are the number and weight fractions of dimer, trimer and tetramerat this point in the reaction?c) Because of the polymerization by dehydration to olefin, 3 mol% of thediol will be lost. What would be the number-average molecular weightwhen the reaction is carried out to the same extent? How could you offsetthis loss so that the desired molecular weight
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
You are asked to manufacture 10 kg of polyester with a number-
average molecular weight of 1000 by polymerizing butane-1,4-diol
(HO(CH2)4OH) with adipic acid (HOOC-(CH2)4-COOH).
a) What weight of diol and diacid do you need, respectively? To what
extent, p, should the reaction be carried out to? Assume a stoichiometric
balance.
b) What are the number and weight fractions of dimer, trimer and tetramer
at this point in the reaction?
c) Because of the polymerization by dehydration to olefin, 3 mol% of the
diol will be lost. What would be the number-average molecular weight
when the reaction is carried out to the same extent? How could you offset
this loss so that the desired molecular weight
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