Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 8, Problem 8.3P
Interpretation Introduction
Interpretation: Double bonds for which stereoisomers are possible are to be stated.
Concept introduction: If there are two different groups attached to a double bond, then it can exhibit stereoisomerism. If there are same groups attached to a double bond, then that double bond cannot show stereoisomerism.
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For which alkenes are stereoisomers possible?
a.
b. CH,CH,CH=CHCH3
C.
-CH CH
d. Cis and trans isomer of CH;CH,CH,CH=CHCH,CH3.
ÇH3
e. E and Z isomers of CH3CH2CH=CCH;CH,CH,
Draw the condensed structures and give the systematic names for all the alkenes with molecular formula C6H12, ignoring stereoisomers. (Hint: There are 13.)
b. Which of the alkenes have E and Z isomers?
c. Which of the alkenes is the most stable? d. Which of the alkenes is the least stable?
Chapter 8 Solutions
Organic Chemistry
Ch. 8 - Label the and carbons in each alkyl halide. Draw...Ch. 8 - Problem 8.2 Classify each alkene in the following...Ch. 8 - Prob. 8.3PCh. 8 - Prob. 8.4PCh. 8 - Problem 8.5 Label each pair of alkenes as...Ch. 8 - Prob. 8.6PCh. 8 - Problem 8.7 Several factors can affect alkene...Ch. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.10P
Ch. 8 - Prob. 8.11PCh. 8 - What alkenes are formed from each alkyl halide by...Ch. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Problem 8.15 How does each of the following...Ch. 8 - Prob. 8.16PCh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Problem 8.19 Explain why...Ch. 8 - Prob. 8.21PCh. 8 - Draw the alkynes formed when each dihalide is...Ch. 8 - Prob. 8.23PCh. 8 - Draw a stepwise mechanism for the following...Ch. 8 - 8.24 Rank the alkenes shown in the ball-and-stick...Ch. 8 - Prob. 8.26PCh. 8 - 8.26 What is the major E2 elimination product...Ch. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31PCh. 8 - PGF2 is a prostaglandin, a group of compounds that...Ch. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - What alkene is the major product formed from each...Ch. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - 8.42 In the dehydrohalogenation of...Ch. 8 - Prob. 8.46PCh. 8 - Prob. 8.47PCh. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Draw the products of each reaction. a.c. b.d.Ch. 8 - Draw the structure of a dihalide that could be...Ch. 8 - Under certain reaction conditions, 2,...Ch. 8 - For which reaction mechanisms, SN1, SN2, E1 or...Ch. 8 - Draw the organic products formed in each reaction....Ch. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Draw all products, including stereoisomers, in...Ch. 8 - Draw all of the substitution and elimination...Ch. 8 - Prob. 8.60PCh. 8 - 8.59 Draw a stepwise, detailed mechanism for each...Ch. 8 - Draw the major product formed when...Ch. 8 - Draw a stepwise, detailed mechanism for the...Ch. 8 - Explain why the reaction of with gives ...Ch. 8 - Draw a stepwise detailed mechanism that...Ch. 8 - Prob. 8.66PCh. 8 - 8.65 Explain the selectivity observed in the...Ch. 8 - Prob. 8.68PCh. 8 - Although dehydrohalogenation occurs with anti...Ch. 8 - 8.68 (a) Draw all products formed by treatment of...
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- Which of the following is NOT an alkyne? a. HC=CH b. HC=C-CH;CH3 с. H3C-C=C-CH3 d.arrow_forwardGive the structure of an alkane that fi ts each description. a. an alkane that contains only 1 ° and 4 ° carbons b. a cycloalkane that contains only 2 ° carbons c. an alkane of molecular formula C 6H 14 that contains a 4 ° carbon d. a cycloalkane that contains 2 ° and 3 ° carbonsarrow_forwardGive the IUPAC name for each. a. I have 5-bromo-3methylheptanearrow_forward
- Determine whether each compound exhibits optical isomerism. a. CCI4 b. CH3-CH2-CH-CH;-CH;-CH;-CH3 c. H CH3-C-CI NH2 d. CH,CHCICH,arrow_forward30. Which of the following alkenes is capable of forming cis-trans isomers? a. CH3CH=CH₂ b. CHI = CHBr c. (CH3)2C=CH2 d. (CH3)₂C=CHI e. CH3CH = CI₂arrow_forward8. Name each alkyne. A. CH3CH2CH2C=CH B. CH3CH2CH2C=CCH3arrow_forward
- Name each alkyne. CH,-C=C-CH, CH3 b. CH;-C=C-C-CH,-CH, CH3 c. CH=C-CH-CH2-CH2-CH, CH-CH, ČH,arrow_forwardDetermine whether each compound exhibits optical isomerism. a. CCI4 b. CH3-CH2-CH-CH,–CH2-CH,-CH3 CH3 с. CH3-C-Cl NH2 d. CH;CHCICH3arrow_forward4. Name the following compounds: a. CH,CH,CH,CH; CH, CH, M CH3 CH2 ČH2 CH3 b. CH-CH-C C-CH, CH, CH2 CH2 CH3 ČH3 CH2 ČH3 с. CН,CH,CH,CH-CH, d.arrow_forward
- Give small explanation.arrow_forward1. Alkene A is ___ stable than alkene B and will release ___ energy when it is hydrogenated to form 2,5-dimethylheptane.arrow_forward7. C=C. A hydrocarbon that contains a -C=C- or the above group. Oa. addition reaction Ob. aliphatic compound C. alkene Od. alkyne e. aromatic hydrocarbon f. hydration g. hydrogenation h. monomer i. phenyl group j. polycyclic aromatic hydrocarbon Ok. polymer O1. unsaturated hydrocarbonarrow_forward
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